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20 ml of an H2 O2 solution on reaction w...

`20 ml` of an `H_2 O_2` solution on reaction with excess of acidified `KMnO_4` released `224` cc of `O_2`. What is the volume strength of that `H_2 O_2` ?

A

5.6 vol

B

11.2 vol

C

22.4 vol

D

2.8 vol

Text Solution

Verified by Experts

The correct Answer is:
A

`2MnO_4^(-) + 5H_2 O_2 + 6H^+ rarr 2 Mn^(2+) + 5O_2 + 8 H_2O`
`22,400 "ml of" O_2 -= 34 g of H_2 O_2`
`224` ml of `O_2 -= 0.34 g of H_2 O_2`
Normality `= (0.34)/(17) xx (1000)/(20) = 1`
Volume strength `= (5.6) (N) = 5.6 Vol`.
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The strength of H_(2)O_(2) is expressed in several ways like molarity, normality,% (w/V), volume strength, etc. The strength of "10 V" means 1 volume of H_(2)O_(2) on decomposition gives 10 volumes of oxygen at 1 atm and 273 K or 1 litre of H_(2)O_(2) gives 10 litre of O_(2) at 1 atm and 273 K The decomposition of H_(2)O_(2) is shown as under : H_(2)O_(2)(aq) to H_(2)O(l)+(1)/(2)O_(2)(g) H_(2)O_(2) can acts as oxidising as well as reducing agent. As oxidizing agent H_(2)O_(2) is converted into H_(2)O and as reducing agent H_(2)O_(2) is converted into O_(2) . For both cases its n-factor is 2. :. "Normality " "of" H_(2)O_(2) "solution" =2xx "molarity of" H_(2)O_(2) solution 20mL of H_(2)O_(2) solution is reacted with 80 mL of 0.05 MKMnO_(4) "in acidic medium then what is the volume strength of" H_(2)O_(2) ?

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