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Geometrical isomerism is found in coordi...

Geometrical isomerism is found in coordination compounds having coordination number:

A

(a) `6`

B

(b) `3`

C

(c) `4`(tetrahedral)

D

(d) `2`

Text Solution

Verified by Experts

The correct Answer is:
A

Geometrical isomerism is found is compound having coordination no. 4 (square planar and not tetrahedral shape) as well as coordination no. 6
Coordination no. 4(square planar) `M_(A_2BC),M_(A_2B_2)`
Showing geometrical isomerism `M_(ABCD)`
Coordination no. 6 (octahedral) `M_(A_4B_2), M_(A_4BC)`
Showing geometrical isomerism `M_(A_3B_3), M_(( A A)_2B_2)`
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Assertion : Complexes of MX_(6) and MX_(5)L type (X and L are unidentate) do not show geometrical isomerism. Reason : Geometrical isomerism is not shown by complexes of coordination number 6.

Knowledge Check

  • Geometrical isomerism in coordination compounds is exhibited by

    A
    Square planar and tetrahedral complexes
    B
    Square planar and octahedral complexes
    C
    Tetrahedral and octahedral complexes
    D
    Square planar, tetrahedral and octahedral complexes
  • Geometrical isomerism in coordination compounds is exhibited by :

    A
    Square planar and tetrahedral complexes
    B
    Square planar and octahedral complexes
    C
    Tetrahedral and octahedral complexes
    D
    Square planar, tetrahedral and octahedral complexes
  • Geometrical isomerism in coordination compounds is exhibited by :

    A
    Square planar and tetrahedral complexes
    B
    Square planar and octahedral complexes
    C
    Tetrahedral and octahedral complexes
    D
    Square planar, tetrahedral and octahedral complexes
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    Geomerical isomerism is not observed in complexes of coordination number 4 of____________geometry .

    Geometrical Isomerism In Cyclic Compounds

    Statement-1: Complexes of MX_(6)" and "MX_(5)L type (X and L are unidentate) do not show geometrical isomerism. Statement-2: Geometrical isomerism is not shown by complexes of coordination number 6.

    Assertion (A) Complexes of MX_(6) and MX_(5)L type (X and L are unidentate) do not show geometrical isomerism. Reason (R) Geometrical isomerism is not shown by complexes of coordination number 6.

    Statement-1: Complexes of MX_(6)" and "MX_(5)L type (X and L are unidentate) do not show geometrical isomerism. Statement-2: Geometrical isomerism is not shown by complexes of coordination number 6.