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The square planar complex (MABCD) can sh...

The square planar complex `(MABCD)` can show

A

(a) two optical isomers

B

(b) three geometrical isomers

C

(c) two geometrical isomers

D

(d) three optical isomers

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The correct Answer is:
B
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The square planar complexes are

Square planar complexes are formed by d^(8) ions with strong field ligands The crystal field splitting Delta_(0) is larger for the second and theird row transition elements and for more highly charged species All the complexes having 4d^(8) and 5d^(8) configurations are mostly square planar including those with weak field ligands such as halide ions square planar complexes can show geometrical isomerism but they do not show optical isomerism due to the presence of plane of symmetry (a) All are low spin complexes (b) [Ni(CO)_(4)] (c) [Pt(NH_(3))_(4)]^(2+) (d) [Ni(NH_(3))_(6)]^(2+) .

The number of geometical isomers possible for a square planar complex [MABCD]^(pmn) are

Which of the following types of square planar complexes can't show geometric isomerism ?

Square planar complexes are formed by d^(8) ions with strong field ligands The crystal field splitting Delta_(0) is larger for the second and theird row transition elements and for more highly charged species All the complexes having 4d^(8) and 5d^(8) configurations are mostly square planar including those with weak field ligands such as halide ions square planar complexes can show geometrical isomerism but they do not show optical isomerism due to the presence of plane of symmetry Among the following complexes which has a square planar geometry? (a) [RhCI(CO)(PPh_(3))_(2)] (b) K_(3)[Cu(CN)_(4)] (c ) [Ni(CO)_(4)] (d) K_(2)[Zn(CN)_(4)] .

The planar complex Mabcd gives

A square planar complex represented as:

Assertion: All square planar complexes can exhibit geometrical isomerism Reason: In square planar complexes .

A: All square planar complexes can exhibit geometrical isomerism. R: In square planar complexes metal assumes sp^(3) hybridisation.

A2Z-COORDINATION COMPOUNDS-Structural Isomerism
  1. The type of isomerism shown by [Co(en)2(NCS)2]Cl and [Co(en)2(NCS)Cl]N...

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  2. Which of the following square planar complexes will form two geometric...

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  3. The square planar complex (MABCD) can show

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  4. Out of the following which will not show geometrical isomerism?

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  5. [Co(NH3)4Cl2]^(+) exhibits

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  6. The Type of isomerism present in pentaammine nitro chromium(III) perch...

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  7. The most stable ion is .

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  8. Which of the following complex ions has geometrical isomers?

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  9. Which of the following pairs represents linkage isomers?

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  10. The number of geometrical isomers of [Co(NH3)3(NO3)3] are:

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  11. A square planar complex is represented as:

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  12. The two compounds sulphato penta-ammine cobalt (III) bromide and sulph...

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  13. Cis-trans isomerism is found in square planar complexes of molecular f...

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  14. Which one of the following is an example of coordination isomerism?

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  15. A square planar complex represented as:

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  16. A compound has the empirical formula CoCl(3).5NH3. When an aqueous sol...

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  17. The isomer

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  18. Which of the following octahedral complex does not show geometrical is...

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  19. [Co(NH3)5NO2]Cl2 and [Co(NH3)5(ONO)Cl2] are related to each other as

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  20. [Co(NH3)5Br]SO4 and [CO(NH3)5SO4]Br are examples of which type of isom...

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