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Which one of the following is an example...

Which one of the following is an example of coordination isomerism?

A

(a) `[Co(NH_3)_5Br]SO_4` and `[Co(NH_3)_5SO_4]Br`

B

(b) `[Co(NH_3)_5NO_2]Cl_2` and `[Co(NH_3)_5ONO]Cl_2`

C

(c) `[Cr(H_2O)_6]Cl_3` and `[Cr(H_2O)_5Cl]Cl_2H_2O`

D

(d) `[Co(NH_3)_6][Cr(CN)_6]` and `[Cr(NH_3)_6][Co(CN)_6]`

Text Solution

Verified by Experts

The correct Answer is:
D
This isomerism is caused by the inter change of ligands between the two complex ions of the same complex
`[Co(NH_3)_6].[Cr(CN)_6]` and `[Cr(NH_3)_6].[Co(CN)_6]`
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A2Z-COORDINATION COMPOUNDS-Structural Isomerism
  1. Which of the following complex ions has geometrical isomers?

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  2. Which of the following pairs represents linkage isomers?

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  3. The number of geometrical isomers of [Co(NH3)3(NO3)3] are:

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  4. A square planar complex is represented as:

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  5. The two compounds sulphato penta-ammine cobalt (III) bromide and sulph...

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  6. Cis-trans isomerism is found in square planar complexes of molecular f...

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  7. Which one of the following is an example of coordination isomerism?

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  8. A square planar complex represented as:

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  9. A compound has the empirical formula CoCl(3).5NH3. When an aqueous sol...

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  10. The isomer

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  11. Which of the following octahedral complex does not show geometrical is...

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  12. [Co(NH3)5NO2]Cl2 and [Co(NH3)5(ONO)Cl2] are related to each other as

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  13. [Co(NH3)5Br]SO4 and [CO(NH3)5SO4]Br are examples of which type of isom...

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  14. [CO(NH3)4Cl2]NO2 and [Co(NH3)4Cl*NO2]Cl are……………isomers

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  15. Which would exhibit ionisation isomerism?

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  16. Coordination isomerism is caused by the interchange of ligands between...

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  17. Which one of the following will not show geometrical isomerism?

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  18. [Co(NH3)4Cl2]^(+) exhibits

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  19. The number of geometrical isomers for [Pt(NH3)2Cl2] is

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  20. The number of geometrical isomers of the complex [Co(NO2)2(NH3)2] is

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