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The hybridization of Fe in K4[Fe(CN)6] c...

The hybridization of `Fe` in `K_4[Fe(CN)_6]` complex is:

A

(a) `d^2sp^2`

B

(b) `dsp^2`

C

(c) `d^2sp^3`

D

(d) `sp^3`

Text Solution

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The correct Answer is:
To determine the hybridization of iron in the complex \( K_4[Fe(CN)_6] \), we can follow these steps: ### Step 1: Determine the oxidation state of iron (Fe) 1. The complex \( K_4[Fe(CN)_6] \) contains 4 potassium ions (K) and 6 cyanide ions (CN). 2. Each potassium ion has a charge of +1, contributing a total charge of +4. 3. Each cyanide ion has a charge of -1, contributing a total charge of -6. 4. The overall charge of the complex is neutral, so we can set up the equation: \[ \text{Charge of Fe} + 4 (\text{from K}) + 6 (\text{from CN}) = 0 \] \[ \text{Charge of Fe} + 4 - 6 = 0 \] \[ \text{Charge of Fe} = +2 \]

To determine the hybridization of iron in the complex \( K_4[Fe(CN)_6] \), we can follow these steps: ### Step 1: Determine the oxidation state of iron (Fe) 1. The complex \( K_4[Fe(CN)_6] \) contains 4 potassium ions (K) and 6 cyanide ions (CN). 2. Each potassium ion has a charge of +1, contributing a total charge of +4. 3. Each cyanide ion has a charge of -1, contributing a total charge of -6. 4. The overall charge of the complex is neutral, so we can set up the equation: \[ ...
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Knowledge Check

  • In K_4Fe(CN)_6

    A
    (a) `(CN)` is linked with primary valency
    B
    (b) `(CN)` is linked with secondary valency
    C
    (c) K is linked with secondary valency
    D
    (d) K is linked with non-ionic valency
  • The hybridisation of Fe in K_(4)[Fe(CN)_(6)] is

    A
    `dsp^(2)`
    B
    `sp^(3)`
    C
    `d^(2)sp^(3)`
    D
    `sp^(3)d^(2)`
  • Hybridization of Fe in K_(3)Fe(CN)_(6) is

    A
    `sp^(3)`
    B
    `dsp^(3)`
    C
    `sp^(3)d^(2)`
    D
    `d^(2)sp^(3)`
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