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The hybridization of Fe in K4[Fe(CN)6] c...

The hybridization of `Fe` in `K_4[Fe(CN)_6]` complex is:

A

(a) `d^2sp^2`

B

(b) `dsp^2`

C

(c) `d^2sp^3`

D

(d) `sp^3`

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The correct Answer is:
To determine the hybridization of iron in the complex \( K_4[Fe(CN)_6] \), we can follow these steps: ### Step 1: Determine the oxidation state of iron (Fe) 1. The complex \( K_4[Fe(CN)_6] \) contains 4 potassium ions (K) and 6 cyanide ions (CN). 2. Each potassium ion has a charge of +1, contributing a total charge of +4. 3. Each cyanide ion has a charge of -1, contributing a total charge of -6. 4. The overall charge of the complex is neutral, so we can set up the equation: \[ \text{Charge of Fe} + 4 (\text{from K}) + 6 (\text{from CN}) = 0 \] \[ \text{Charge of Fe} + 4 - 6 = 0 \] \[ \text{Charge of Fe} = +2 \]

To determine the hybridization of iron in the complex \( K_4[Fe(CN)_6] \), we can follow these steps: ### Step 1: Determine the oxidation state of iron (Fe) 1. The complex \( K_4[Fe(CN)_6] \) contains 4 potassium ions (K) and 6 cyanide ions (CN). 2. Each potassium ion has a charge of +1, contributing a total charge of +4. 3. Each cyanide ion has a charge of -1, contributing a total charge of -6. 4. The overall charge of the complex is neutral, so we can set up the equation: \[ ...
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A2Z-COORDINATION COMPOUNDS-Wemer Theory And Vbt
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  2. Ag^(o+) forms complexes:[Ag(NH(3))(2)]^(o+),[Ag(CN)(2)]^(Θ),[Ag(S(2)O(...

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  3. The hybridization of Fe in K4[Fe(CN)6] complex is:

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  4. The structure of iron pentacarbonyl is:

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  5. [Cr(NH3)6]^(3+) ion is:

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  6. In hexacyanidomanganate(II) ion the Mn atom assumes d^(2)sp^(3)- hybri...

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  7. Which is true in the case of [Ni(CO)4] complex?

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  8. Which one of the following is an outer orbital complex and exhibits pa...

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  9. Which of the following complexes exhibits the highest paramagnetic beh...

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  10. A magnetic moment of 1.73 B.M. will be shown by one among the followin...

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  11. A square planar complex is formed by hybridization of which atomic orb...

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  12. Among the following complexes : K(3)[Fe(CN)(6)],[Co(NH(3))(6)]Cl(3) , ...

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  13. Consider the follwing complexes ion P,Q and R P =[FeF(6)]^(3-), Q=[V...

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  14. Among the following ions which one has the highest paramagnetism?

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  15. The reaction [Fe(CNS)6]^(3-)rarr[FeF6]^(3-) takes place with:

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  16. dsp^2-hybridization is found in

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  17. The primary valency of iron in K4[Fe(CN)6] is

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  18. The magnetic moment of K3[Fe(CN)6] is found to be 1.7 B.M. How many un...

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  19. [Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a magnetic moment of 3.83 B.M. ...

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  20. Which of the following complex is an outer orbital complex?

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