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[Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a...

`[Cr(H_2 O)_6]Cl_3` (at no. of Cr = 24) has a magnetic moment of `3.83 B.M`. The correct distribution of `3d` electrons the chromium of the complex.

A

(a) `3dxy^1`, `3dyz^1`, `3dz^2`

B

(b) `3d^1xy`, `3d^1yz`, `3d^1zx`

C

(c) `3d_((x^2-y^2)^1), 3d^1z^2, 3d^1xz`

D

(d) `3dxy^1`, `3d^1x^2-y^2`, `3d^1y^2`

Text Solution

Verified by Experts

The correct Answer is:
B

`3.83=sqrt(n(n+2))` so, `n=3`
So, these are three unpaired `e^(-)s`. Based on crystal field splitting the orbital of `t_(29)` set have one `e^(-)` each.
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