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Which of the following complex is an out...

Which of the following complex is an outer orbital complex?

A

(a) `[Ni(NH_3)_6]^(2+)`

B

(b) `[Mn(CN)_6]^(4-)`

C

(c) `[Co(NH_3)_6]^(3+)`

D

(d) `[Fe(CN)_6]^(4-)`

Text Solution

Verified by Experts

The correct Answer is:
A

`Ni` in `[Ni(NH_3)_6]^(2+)` has `sp^3d^2` (outer complex) having octahedral geometry.
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A2Z-COORDINATION COMPOUNDS-Wemer Theory And Vbt
  1. The magnetic moment of K3[Fe(CN)6] is found to be 1.7 B.M. How many un...

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  2. [Cr(H2 O)6]Cl3 (at no. of Cr = 24) has a magnetic moment of 3.83 B.M. ...

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  3. Which of the following complex is an outer orbital complex?

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  4. The correct order of magnetic moments (spin values in B.M.) among is:

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  5. Which of the following has the regular tetrahedral structure?

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  6. Which one of the following has lowest value of paramagnetic behaviour?

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  7. Velence bond theroy describes the bonding in complexs in terms of coor...

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  8. Nickel (Z=28) combines with a uninegative monodentate ligand X^(-) to ...

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  9. Which one of the following has a square planar geometry? (Co=27, Ni=...

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  10. The octahedral complex of a metal ion M^(3+) with four monodentate lig...

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  11. Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong?

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  12. The magnetic moment (spin only) of [NiCl4]^(2+) is

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  13. Which of the following is a low spin complex?

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  14. Complexes with halide ligands are generally:

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  15. Among the following ions, which one has the highest paramagnetism?

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  16. Among [Ni(CO)4], [Ni(CN)4]^(2-), [NiCl4]^(2-) species, the hybridizati...

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  17. Which is correct in the case of [NiCl4]^(2-) complex?

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  18. The shape of [Cu(NH3)4]Cl2 is:

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  19. For which transition metal ions are low spin complexes possible:

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  20. An octahedral complex is formed when hybrid orbitals of the following ...

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