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Among [Ni(CO)4], [Ni(CN)4]^(2-), [NiCl4]...

Among `[Ni(CO)_4], [Ni(CN)_4]^(2-), [NiCl_4]^(2-)` species, the hybridization states at the `Ni` atom are, respectively (At. no.of `Ni=28`)

A

(a) `Ni(CO)_4` and `NiCl_4^(2-)` are diagmagnetic and `Ni(CN)_4^(2-)` is paramagnetic

B

(b) `NiCl_4^(2-)` and `Ni(CN)_4^(2-)` are diamagnetic and `Ni(CO)_4` is paramagnetic

C

(c) `Ni(CO)_4` and `Ni(Cl)_4^(2-)` are diamagnetic and `Ni(CN)_4^(2-)` is paramagnetic

D

(d) `Ni(CO)_4` is diamagentic and `NiCl_4^(2-)` and `Ni(CN)_4^(2-)` are paramagnetic

Text Solution

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The correct Answer is:
C

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A2Z-COORDINATION COMPOUNDS-Wemer Theory And Vbt
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  2. Which one of the following has lowest value of paramagnetic behaviour?

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  3. Velence bond theroy describes the bonding in complexs in terms of coor...

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