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Which of the following alkanes cannot ha...

Which of the following alkanes cannot have conformations?

A

`(CH_(3))_(4)C`

B

`(CH_(3))_(3)CH`

C

`CH_(4)`

D

`(CH_(3))_(2)CHCH_(2)CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
C

To exhibit conformational isomerism, the molecule of a compound must have at least four atoms ( same or different) bonded sequentially only by sigma bonds, i.e., `R - D - S - V`. Methane `(CH_(4))` cannot have conformations as only three atoms are bonded sequentially `(H-underset(H)underset(|)overset(H)overset(|)C-H)`. Conformations are also exhibited by inorganic compounds, e.g., `H_(2)O_(2), H_(2)NOH`.
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