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The oldest synthetic method of phenol is...

The oldest synthetic method of phenol is the alkali fusion of

A

sodium phenoxide

B

sodium benzenesulphonate

C

sodium benzenecarboxylate

D

Phenyl sodium

Text Solution

Verified by Experts

The correct Answer is:
B

Alkali fusion of the sulphonate salt :
`PhHoverset(H_(2)S_(2)O_(7))rarrPhSO_(3)H underset(2.H^(+))overset(1.NaOH ,330^(@)C)rarrPhOH`
Benzene is suphonated with oleum `(H_(2)SO_(4)//SO_(3))` and benzene sulphonic acid is converted to sodium phenoxide on heating with molten sodium hydroxide.Acidification of the sodium salt gives phenol
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