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Consider the following sequence of react...

Consider the following sequence of reactions
`CH_(2)=CHCH=CH_(2)underset(C CI_(4))overset(Br_(2)(1mol e))rarrA underset(2H_(2),Ni)overset(1KCN(excess))rarrB` .

A

`CH_(2)=CH-overset(NH_(2))overset(||)CH-CH_(2)NH_(2)`

B

`NC CH_(2)CH=CHCH_(2)CH`

C

`H_(2)N(CH_(2))_(6)NH_(2)`

D

`CH_(2)=CH-underset(CH_(2)NH_(2))underset(|)CH_(2)-CH_(2)NH_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

First step involves `1,4-`addition of `Br_(2)` to yield to dibromide which undergoes nuclephilic substitution to yield dicyanide which yields diamine on reduction
.
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R SHARMA-AMINES-Follow -up Test
  1. The end product (B) of the reaction .

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  2. The end product (B) of the reaction sequence is .

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  3. Consider the following sequence of reactions CH(2)=CHCH=CH(2)underse...

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  4. CH(3)CH(2)OHunderset(H(2)SO(4))overset(K(2)Cr(2)C(2))rarrA overset(SOC...

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  5. C(6)H(5)CH(2)Ioverset(NaN(3))rarrA underset(2H(2)O)overset(1.LAH)rarrB...

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  6. H(2)C=CHCH(2)Br+N(3)^()rarrAunderset(1LiAIH(4))overset(2.H(2)O)rarrB ...

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  7. CH=CHunderset(42%H(2)SO(4))overset(1%HgSO(4))rarrAunderset(Delta,press...

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  8. CH(3)CNunderset(2.steam distillation)overset(1.SnCI(2)//HCI)rarrA unde...

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  9. Which of the following reactions leads to the formation of a primary a...

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  10. Gabried synthesis is not a viable method for preparing (i) t- butyla...

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  11. Acetamide is treated separaately with the following reagents Which one...

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  12. Among the following compounds the one which will produce 1-phenylethan...

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  13. The reaction of (S)-2 methybutanamide with Br(2) and Ohbar produces on...

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  14. Consider the following sequence of reactions CH(3)COOH overset(SOCI(...

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  15. In the following sequence of reactions (CH(3))(2)CO underset(H(2)SO(...

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  16. Ritter reaction is a good method for preparing primary amines containi...

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  17. The end prouct (B) formed in the reaction RNCoverset(HgO)rarrAunders...

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  18. Which of the following reacts with Grignard reagent to yield a primar...

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  19. The reactionCH(3)I+NH(3)(excess)underset(2.OHbar)overset(1.heat)rarrCH...

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  20. Predict the product of the following reaction C(6)H(5)CH(2)I underset(...

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