Home
Class 12
CHEMISTRY
H(2)C=CHCH(2)Br+N(3)^()rarrAunderset(1Li...

`H_(2)C=CHCH_(2)Br+N_(3)^(_)rarrAunderset(1LiAIH_(4))overset(2.H_(2)O)rarrB`
Identify compound `B` .

A

`CH_(3)CH_(2)CH_(2)NH_(2)`

B

`CH_(3)CH(NH_(2))CH_(3)`

C

`CH_(2)=CHCH_(2)NH_(2)`

D

`H_(2)NCH_(2)CH_(2)CH_(2)NH_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

A is `H_(2)C=CHCH_(2)N_(3)` formed bt `S_(N)2` displacement of `Brbar` by `N_(3)bar` B is `H_(2)C=CHCH_(2)NH_(2)` because `LiAIH_(4)` does not reduce the double bond it reduces only the azide group Note that alky1 azides are explosives They should not be isolated but be reacted only in situ .
Promotional Banner

Topper's Solved these Questions

  • AMINES

    R SHARMA|Exercise Follow -up Test 3|1 Videos
  • AMINES

    R SHARMA|Exercise Follow -up Test 4|1 Videos
  • AMINES

    R SHARMA|Exercise Follow -up Test 2|1 Videos
  • ALCOHOL, PHENOL AND ETHERS

    R SHARMA|Exercise ETHERS level IV|7 Videos
  • BIOMOLECULES

    R SHARMA|Exercise Archives|47 Videos

Similar Questions

Explore conceptually related problems

In the following sequence of reactions, the alkene affords the compound B : CH_(3)CH=CHCH_(3)overset(O_(3))rarrAunderset(Zn)overset(H_(2)O)rarrB The compound B is

Identify the compound C in the following sequence: (CH_(3))_(2) CHCH_(2)C-=N overset(HCI,H_(2)O)rarr compound A overset(1.LiAIH_(4))underset(2.H_(2)O)rarr compound B overset(PC C)underset(CH_(2)CI_(2))rarr compound C

C_(3)H_(7)CH=CH_(2)underset(THF//H_(2)O)overset(Hg(OAc)_(2))rarrAunderset(NaOH)overset(NaBH_(4))rarrB The compound B is

CH_(3)_(2)C=C(CH_(3))_(2)overset(CI_(2)//H_(2)O)rarrAoverset(OH^(-))rarrB .Identify B

RF overset(SbF_(5))(rarr) Aoverset(H_(2)o)rarrB Identify the product B

Consider the following sequence of reactions. underset(H^(+))overset(HOCH_(2).CH_(2)OH)rarrAunderset(2.H_(3)O^(+))overset(1.LiAIH_(4),Et_(2)O)rarrB The products (A) and (B) are, respevtively.

Consider the following reaction. CH_(2)=CHCH_(2)Br overset(Mg//"dry ether")rarrAunderset((ii)H_(3)O^(+))overset((i)CO_(2))rarrX The compound X is

The major end product B in the reaction C_(6)H_(5)CH_(2)Br overset(AgNO_(2))rarrA underset(2.H_(3)O^(+))overset(1.LiAIH_(4))rarrB is .

R SHARMA-AMINES-Follow -up Test
  1. CH(3)CH(2)OHunderset(H(2)SO(4))overset(K(2)Cr(2)C(2))rarrA overset(SOC...

    Text Solution

    |

  2. C(6)H(5)CH(2)Ioverset(NaN(3))rarrA underset(2H(2)O)overset(1.LAH)rarrB...

    Text Solution

    |

  3. H(2)C=CHCH(2)Br+N(3)^()rarrAunderset(1LiAIH(4))overset(2.H(2)O)rarrB ...

    Text Solution

    |

  4. CH=CHunderset(42%H(2)SO(4))overset(1%HgSO(4))rarrAunderset(Delta,press...

    Text Solution

    |

  5. CH(3)CNunderset(2.steam distillation)overset(1.SnCI(2)//HCI)rarrA unde...

    Text Solution

    |

  6. Which of the following reactions leads to the formation of a primary a...

    Text Solution

    |

  7. Gabried synthesis is not a viable method for preparing (i) t- butyla...

    Text Solution

    |

  8. Acetamide is treated separaately with the following reagents Which one...

    Text Solution

    |

  9. Among the following compounds the one which will produce 1-phenylethan...

    Text Solution

    |

  10. The reaction of (S)-2 methybutanamide with Br(2) and Ohbar produces on...

    Text Solution

    |

  11. Consider the following sequence of reactions CH(3)COOH overset(SOCI(...

    Text Solution

    |

  12. In the following sequence of reactions (CH(3))(2)CO underset(H(2)SO(...

    Text Solution

    |

  13. Ritter reaction is a good method for preparing primary amines containi...

    Text Solution

    |

  14. The end prouct (B) formed in the reaction RNCoverset(HgO)rarrAunders...

    Text Solution

    |

  15. Which of the following reacts with Grignard reagent to yield a primar...

    Text Solution

    |

  16. The reactionCH(3)I+NH(3)(excess)underset(2.OHbar)overset(1.heat)rarrCH...

    Text Solution

    |

  17. Predict the product of the following reaction C(6)H(5)CH(2)I underset(...

    Text Solution

    |

  18. Consider the following sequence of reactions underset(base)overset(C...

    Text Solution

    |

  19. The end product C in the following sequence of reactions CaNCN ove...

    Text Solution

    |

  20. Predict the end product of the following sequence of reactions C(6)...

    Text Solution

    |