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Which of the following compounds gives a...

Which of the following compounds gives a tertiary amine on reduction ? .

A

Nitriles

B

Amides

C

Oximes

D

Nitroalkanes

Text Solution

Verified by Experts

The correct Answer is:
B

Reduction of a nitrile an oxime or a nitroalkane yields a primary amine whereas eeducation of an amide can yield a primary secondary or tertiary amine Reduction of N,N-disubstituted primary amide converts the carbony1 group `(C=O)` into methylene group `(CH_(2))` to yield a tertiary amine
`CH_(3)CH_(2)-overset(O)overset(||)C-underset(CH_(3))underset(|)N-CH_(3)underset(2H_(2)O)overset(1LiAIH_(4) ether)rarrCH_(3)CH_(2)CH_(2)- underset(3^(@) amine)underset(CH_(3))underset(|)N-CH_(3)` .
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R SHARMA-AMINES-Follow -up Test
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  2. The major product (X) of the reaction CH(3)CH(2)NH(2)+HCHO+HCOOHover...

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  3. Which of the following compounds gives a tertiary amine on reduction ?...

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  4. When tetramethylammonium hydroxide is heated in aqueous solution under...

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  5. The major product (X) of the reaction (CH(3))(3)CNH(2)+underset(exce...

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  6. The end product of the following of reactions is C(6)H(5)underset(Fe...

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  7. An amine (X) on being heated with an excess of methy1 bromide produces...

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  8. Which of the following reagents is used for the Hinsberg method to sep...

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  9. A mixture of ethano1 vapour and ammonia is heated under pressure in th...

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  10. A compound (X) having the molecular formula C(3)H(9)N is insoluble in ...

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  11. Which of the following reagents is employed in the Hofmann s method to...

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  12. In Which of the following compound are intermolecular hydrogen bonds n...

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  13. Among the following isomeric amines which one is expected to have the ...

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  14. Which of the following are soluble in water ? .

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  15. Which of the following is incorrect about amines

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  16. If pK(b) for the reaction of MeNH(2) in water is 3.4 the pK(a) for the...

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  17. Which of the following statements is incorrect .

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  18. Which of the following is water soluble .

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  19. Considering the basic strength in the gas phase which one has the smal...

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  20. Which of the following is the corrent order of basicity in aqueous sol...

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