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An amine (X) on being heated with an exc...

An amine `(X)` on being heated with an excess of methy1 bromide produces diethyldimethy lammonium bromide The amine `(X)` is .

A

`C_(2)H_(5)N(CH_(3))_(2)`

B

`C_(2)H_(5)NHCH_(3)`

C

`(C_(2)H_(5))_(2)NH`

D

`C_(2)H_(5)NH_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

`underset("Diethyldimethy lammonium bromide")(CH_(3)CH_(2)-underset(CH_(2)CH_(3))underset(|)overset(CH_(3))overset(|)(N^(+))-CH_(3)Brbar)`
Since the quaternary salt carries two ethy1 groups the amine `(X)` must be a `2^(@)` amine with two ethy1 groups
`(C_(2)H_(5))_(2)NH underset(Delta)overset(CH_(3)Br (excess))rarr(C_(2)H_(5))_(2)overset(+)N(CH_(3))_(2)Brbar` .
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R SHARMA-AMINES-Follow -up Test
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  7. Which of the following reagents is employed in the Hofmann s method to...

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  10. Which of the following are soluble in water ? .

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  11. Which of the following is incorrect about amines

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  12. If pK(b) for the reaction of MeNH(2) in water is 3.4 the pK(a) for the...

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  13. Which of the following statements is incorrect .

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  14. Which of the following is water soluble .

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  15. Considering the basic strength in the gas phase which one has the smal...

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  16. Which of the following is the corrent order of basicity in aqueous sol...

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  18. Among the following the most basic is

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  19. Which of the following has the highest PK(a) ?

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  20. Which of the folllowing has the highest pK(b) ? .

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