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Which of the following is most basic ?....

Which of the following is most basic ?.

A

`NH_(3)`

B

`C_(6)H_(5)NH_(2)`

C

`Ch_(3)NH_(2)`

D

`C_(6)H_(5)CH_(2)NH_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C
The correct order of basic strength is
`CH_(3)NH_(2) gt C_(6)H_(5)CH_(2)NH_(2) gt C_(6)H_(5)NH_(2)`
In aniline the lone pair on `N` atom is delocalized due to resonance while in methylamine the probability of finding the lone pair on N atom is increased due to the electron releasing nature of `CH_(3)` group .
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Knowledge Check

  • Which of the following si most basic:

    A
    B
    C
    D

  • Which of the foil owing is most basic?

    A
    `CH_(3)CH_(2)NH_(2)`
    B
    `CH_(3)CONH_(2)`
    C
    `C_(6)H_(5)CONHCH_(3)`
    D
    `NH_(2)NH_(2)`

  • Which of the following is the most basic ?

    A
    `p-` phenylenediamine
    B
    `m-`phenylenediamine
    C
    aniline
    D
    `p-`bromoaniline

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