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Which of the following compounds does no...

Which of the following compounds does not liberate nitrogen gas on treatment with nitrous acid ?

A

`CH_(3)NHCH_(3)`

B

`(CH_(3))_(2)CHNH_(2)`

C

`(CH_(3))_(2)NC_(6)H_(5)`

D

Both (1) and (3)

Text Solution

Verified by Experts

The correct Answer is:
D

Only primary aliphatic amines react with nitrous acid to evolve nitrogen gas quantitatively

Even acid amides `(RCONH_(2))` and urea `(H_(2)NCONH_(2))` liberate `N_(2)` gas on reaction with nitrous acid .
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Knowledge Check

  • Which of the following compounds will not liberate nitrogen gas on reaction with nitrous acid ?

    A
    Diethylamine
    B
    Aniline
    C
    N-Phenylmethanamine
    D
    All of these.
  • Which of the following compounds does not give nitrogen on heating?

    A
    `NaN_(3)`
    B
    `(NH_(4))_(2)SO_(4)`
    C
    `NH_(4)NO_(2)`
    D
    `(NH_(4))_(2)Cr_(2)O_(7)`
  • Which of the following compounds does not liberate nitrogen with HNO_(2) ?

    A
    Carbamide
    B
    Primary amine
    C
    Secondary amine
    D
    Alkanamide
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