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Among the diazonium ions the order of re...

Among the diazonium ions the order of reactivity towards diazocoupling with phenol in the presence of dilute `NaOH` is .

A

`IIIltIltIVltII`

B

`IltIVltIIltIII`

C

`IltIIIltIVltII`

D

`IIIltIltIIltIV`

Text Solution

Verified by Experts

The correct Answer is:
C

Since `(B)` is the reactive contributing resonance structure any factore that increases its contribution will increases the reactivity of that diazonium cation Electron withdrawing groups `(NO_(2))` favour `(B)` while electron releasing groups favour (A) thus the order of reactivity is II lt IV lt III lt I Notice that the order of electron releasing power is `Me_(2)NgtCH_(3)OgtCH_(3))`
.
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