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Pheny1 isocyanide is prepared from...

Pheny1 isocyanide is prepared from

A

Wurtz reaction

B

Reimer-Tiemann reaction

C

Carbylamine reaction

D

Rosenmund s reaction

Text Solution

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The correct Answer is:
C

Aliphatic as well as aromatic primary amines on heating with chloroform and ethanolic potssium hydroxide form isocyanides or carbylamines which are foul smelling substances
`underset(ArNH_(2))overset(RNH_(2))or+CHCI_(3)+KOHoverset(Delta)rarroverset(R-NC)underset(Ar-NC)(or+)3KCl+3H_(2)O`
secondary and tertiary amines do not show this reactions which is known as carbylamine reaction .
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