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Consider the following sequence of react...

Consider the following sequence of reactions
Compounds `[A] overset("reducation")rarr [B] overset(HNO_(2))rarrCH_(3)CH_(2)OH` The compound `[A]` is .

A

`CH_(3)CH_(2)CN`

B

`CH_(3)NO_(2)`

C

`CH_(3)NC`

D

`CH_(3)CN`

Text Solution

Verified by Experts

The correct Answer is:
D

The fact that `B` on treatment with nitrous acid yields ethy1 alcoho1 indicates that it must be a primary aliphatic amine Thus
`CH_(3)CM overset("reduction") rarr CH_(3)CH_(2)NH_(2)overset(HNO_(2))rarrCH_(3)CH_(2)OH` .
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