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Which of the following reagents can be u...

Which of the following reagents can be used to convert benzenediazonium chloride into benzene ?

A

`CH_(3)OH`

B

`H_(3)PO_(2)`

C

`Br_(2)//H(2)O`

D

`LiAiH_(4)`

Text Solution

Verified by Experts

The correct Answer is:
B

Hypophophorus acid (phosphinic acid) `H_(3)PO_(2)` reduces diazonium salts to arenes and gets oxidized to phosphoric acid
`ArN_(2)^(+)Cl^(bar)+H_(3)Po_(2)+H_(2)Orarr ArH + N_(2)+H_(3)PO_(3)+HCI`
Since benzenediazonium salts are synthesized in aqueous solution `LiAIH_(4)` can t be used for reduction as t reacts vigorously with water .
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