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Secondary amines could be prepared by...

Secondary amines could be prepared by

A

Reduction of nitriles

B

Hofmann bromamide reaction

C

Reduction of amides

D

Reduction of isonitriles.

Text Solution

Verified by Experts

The correct Answer is:
D

`R-C-=Noverset(4[H])rarrR-CH_(2)NH_(2)`
`RCONH_(2)+Br_(2)+4KOHoverset("heat")rarr`
`R-NH_(2)+2KBr+K_(2)CO_(3)+2H_(2)O`
`ROCNH_(2)overset(4[H])rarrRCH_(2)NH_(2)+H_(2)O`
`R-N-=Coverset(4[H])rarrRNH-CH_(3)`
`R-NO_(2)(6[H])rarrRNH_(2)+2H_(2)O`
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