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KCN reacts readily to give a cyanide wit...

KCN reacts readily to give a cyanide with

A

Ethyl alcohol

B

Ethyl bromide

C

Bromobenzene

D

Chlorobenzene

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The correct Answer is:
To solve the question "KCN reacts readily to give a cyanide with", we need to analyze the reactivity of KCN (potassium cyanide) with different types of compounds. Here’s a step-by-step breakdown of the solution: ### Step 1: Understanding the Components KCN dissociates in solution to form K⁺ and CN⁻ ions. The CN⁻ ion is a strong nucleophile, which means it can attack electrophilic centers in organic compounds. **Hint:** Identify the components of KCN and their roles in the reaction. ### Step 2: Identifying Reactants We need to determine which type of organic compound KCN can react with to form a cyanide. Typically, KCN reacts with alkyl halides, especially primary alkyl halides, through an SN2 mechanism. **Hint:** Consider the types of organic compounds that can undergo nucleophilic substitution. ### Step 3: Analyzing the Options 1. **S.L.L. Alcohol (C2H5OH)**: Alcohols do not react with KCN to form cyanides because they are not good electrophiles for nucleophilic substitution. 2. **S.L. Bromide (CH3CH2Br)**: This is a primary alkyl halide. When KCN reacts with CH3CH2Br, the CN⁻ ion will attack the carbon bonded to the bromine, leading to the formation of ethyl cyanide (CH3CH2CN) and potassium bromide (KBr). 3. **Bromobenzene**: This is an aromatic compound and does not undergo SN2 reactions with KCN due to the stability of the aromatic ring. 4. **Chlorobenzene**: Similar to bromobenzene, chlorobenzene is also not reactive towards KCN due to the aromatic nature. 5. **Ethylbenzene**: This is not a halide and thus cannot react with KCN to form cyanides. **Hint:** Evaluate each option based on the type of reaction (SN2) and the structure of the compound. ### Step 4: Conclusion The only viable option that allows KCN to react and form a cyanide is the primary alkyl halide, which is S.L. Bromide (CH3CH2Br). The reaction will yield ethyl cyanide (CH3CH2CN). **Final Answer:** KCN reacts readily to give a cyanide with S.L. Bromide (CH3CH2Br). ---

To solve the question "KCN reacts readily to give a cyanide with", we need to analyze the reactivity of KCN (potassium cyanide) with different types of compounds. Here’s a step-by-step breakdown of the solution: ### Step 1: Understanding the Components KCN dissociates in solution to form K⁺ and CN⁻ ions. The CN⁻ ion is a strong nucleophile, which means it can attack electrophilic centers in organic compounds. **Hint:** Identify the components of KCN and their roles in the reaction. ### Step 2: Identifying Reactants ...
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(a) Haloalkanes react with potassium cyanide (KCN) to give alkyl cyanide but gives alkyl isocyanide with silver cyanide (AgCN). (b) Why are haloarenes more stable than haloalkanes?

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When ethyl bromide reacts with silver cyanide, the main product will be:

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