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Assertion: In order to convert R-Cl to p...

Assertion: In order to convert R-Cl to pure `R-NH_(2)`, Gabriel pthalimide synthesis can be used.
Reasaon: With proper choice of alkyl halides. Pthalimide synthesis can be used to prepare `1^(@),2^(@)` or `3^(@)` amines.

A

If both assertion and reason are true and the reason is the correct explanantion of the assertion.

B

If both assertion and reason are true but reason is not the correct explanantion of the assertion.

C

If assertion is true but reason is false.

D

If the assertion and reason both are false.

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The correct Answer is:
To solve the question, we will analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that Gabriel phthalimide synthesis can be used to convert R-Cl to pure R-NH2. - Gabriel phthalimide synthesis is a well-known method for synthesizing primary amines from alkyl halides. 2. **Understanding the Reason**: - The reason claims that with the proper choice of alkyl halides, phthalimide synthesis can prepare 1°, 2°, or 3° amines. - However, this statement is misleading because Gabriel phthalimide synthesis primarily yields primary amines (1° amines) and is not suitable for preparing secondary (2°) or tertiary (3°) amines. 3. **Analyzing the Mechanism**: - In Gabriel phthalimide synthesis, phthalimide reacts with a strong base to form a nucleophilic phthalimide anion. - This anion then undergoes an SN2 reaction with a primary alkyl halide (R-X) to form a N-alkyl phthalimide. - Hydrolysis of this intermediate leads to the formation of the primary amine (R-NH2) and phthalic acid. 4. **Conclusion**: - The assertion is true because Gabriel phthalimide synthesis can indeed convert R-Cl to R-NH2. - The reason is false because Gabriel phthalimide synthesis cannot produce secondary or tertiary amines; it is limited to primary amines. ### Final Answer: - **Assertion**: True - **Reason**: False

To solve the question, we will analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that Gabriel phthalimide synthesis can be used to convert R-Cl to pure R-NH2. - Gabriel phthalimide synthesis is a well-known method for synthesizing primary amines from alkyl halides. ...
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