Home
Class 12
CHEMISTRY
Alkyl cyanides undergo Stephen redyction...

Alkyl cyanides undergo Stephen redyction to produce

A

Aldehyde

B

Secondary amine

C

Primary amine

D

Amide

Text Solution

Verified by Experts

The correct Answer is:
A

When a solution of alkyl cyanides in ether is reduced with stannous chloride and hydrochloric acid at room temperature, imine hydrochloric is obtained which on subsequent hydrolysis with boiling water, forms an aldehyde (Stepthen's reduction).
`R-C-=Nunderset(2(H))overset(SnCl_(2)//HCl)rarrRCH=NH.HCloverset(H_(2)O)rarrRCHO`
Promotional Banner

Topper's Solved these Questions

  • NITROGEN CONTAINING COMPOUNDS

    ERRORLESS |Exercise PROPERTIES OF NITROGEN CONTAINING COMPOUNDS|16 Videos
  • NITROGEN CONTAINING COMPOUNDS

    ERRORLESS |Exercise TESTS FOR NITROGEN CONTAINING COMPOUNDS|11 Videos
  • NITROGEN CONTAINING COMPOUNDS

    ERRORLESS |Exercise JEE (ADVANCED) 2018 MORE THAN ONE CHOICE CORRECT ANSWER|1 Videos
  • IONIC EQUILIBRIUM

    ERRORLESS |Exercise JS Jee Section (JEE Advanced (Numeric answer type question))|1 Videos
  • NUCLEAR CHEMISTRY

    ERRORLESS |Exercise JEE SECTION (Matrix Match Type Questions)|2 Videos

Similar Questions

Explore conceptually related problems

All alkyl halides undergo reduction process except

Acetaldol on heating undergo dehydration to produce

What is Stephen reaction ?

Alkyl cyanides can be obtained by

Alkyl cyanide on reduction produces_____________.

Alkyl cyanides upon hydrolysis give :

ERRORLESS -NITROGEN CONTAINING COMPOUNDS -PREPARATION OF NITROGEN CONTAINING COMPOUNDS
  1. When acetamide is hydrolysed by boiling with acid, the product obtaine...

    Text Solution

    |

  2. Which will not go for diazotisation

    Text Solution

    |

  3. Alkyl cyanides undergo Stephen redyction to produce

    Text Solution

    |

  4. On strong heating, ammonium acetate gives

    Text Solution

    |

  5. In the diazotisation of anline with sodium nitrite and hydrochloride a...

    Text Solution

    |

  6. Complete the following reaction: RNH(2)+H(2)SO(4)to

    Text Solution

    |

  7. n-Propylamine yields a volatile compound X on warning with alc alkali ...

    Text Solution

    |

  8. The product formed in the reaction of glycine with benzoyl chloride +a...

    Text Solution

    |

  9. Action of NaNO(2)+dil HCl on ArNH(2) yields ArN(2)^(+)Cl^(-). A simila...

    Text Solution

    |

  10. Which one of the following nitro compounds when react with nitrous aci...

    Text Solution

    |

  11. Which of the following has the smell of bitter almonds

    Text Solution

    |

  12. Identify the product C in the series. C(6)H(5)NO(2) overset(FeHCl) t...

    Text Solution

    |

  13. A compound with nitro group was reduced by Sn//HCl, followed by treatm...

    Text Solution

    |

  14. The reduction of which of the following compound would yield secondary...

    Text Solution

    |

  15. Dye test can be used to distinguish between

    Text Solution

    |

  16. Text Solution

    |

  17. Which of the following is not the property of ethanenitrile (CH3CN) ?

    Text Solution

    |

  18. Amino group, -NH(2) is ortho, para-directing group in case of aromatic...

    Text Solution

    |

  19. Aniline reacts with alktl halide to give

    Text Solution

    |

  20. When an organic compound was treated with sodium nitrite and hydrochlo...

    Text Solution

    |