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Nitration of aniline also gives m-nitro ...

Nitration of aniline also gives m-nitro anilime, in stron acidic medium because,

A

In electrophilic substitution reaction amino group is meta directive

B

Inspite of substituents nitro group always goes to m-position

C

In strong acidic medium, nitration of aniline is a nucleophilic substitution reaction.

D

In strong acidic medim aniline present as anilinium ion

Text Solution

Verified by Experts

The correct Answer is:
D


The reason for this is that, in acidic condition protonation of `-NH_(2)` group gives anilinium ion `(+NH_(3))`, which is of deactivating nature and of m-directing nature.
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ERRORLESS -NITROGEN CONTAINING COMPOUNDS -PREPARATION OF NITROGEN CONTAINING COMPOUNDS
  1. Which one of the following compound is most basic

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  2. Which of the following is capable of forming a zwitter ion ?

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  3. Nitration of aniline also gives m-nitro anilime, in stron acidic mediu...

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  4. Identify the product in the following sequence 3,4,5-tribromoaniline u...

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  5. Which of the following will be obtained on acetylation of aniline

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  6. Which of the following reaction does NOT occur ?

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  7. Presently which reagent is used for separation of 1^(@),2^(@) and 3^(@...

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  8. Which of the following compounds is an amino acid

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  9. Rection of primary amines with aldehyde yields

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  10. Assertion(A) : Aniline hydrogen sulphate on heating froms a mixture of...

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  11. Assertion: Benzene diazonium chloride does not give tests for nitrogen...

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  12. Assertion: Amines are basic in nature. Reason: Presence of ione pair...

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  13. (A) p-O(2)N-C(6)H(4)COCH(3) is prepared by Friedel Crafts acylation of...

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  14. Assertion : Alkyl isocyanides in acidified water give alkyl formamides...

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  15. Assertion : Anilinium choride is more acidic than ammonium chloride. ...

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  16. (A) Amines are more basic than esters and ethers. (R) Nitrogen is le...

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  17. Assertion: Nitrobenzene is used as a solvent in Friedel-Craft's reacti...

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  18. The electrolytic reduction of nitrobenzene in strongly acidic medium p...

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  19. The reaction CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|...

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  20. Consider the nitratio of benzene using mixed conc. H(2)SO(4) and HNO(3...

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