Home
Class 12
CHEMISTRY
Assertion: Nitrobenzene is used as a sol...

Assertion: Nitrobenzene is used as a solvent in Friedel-Craft's reaction.
Reason: Fusion of nitrobenzene with solid KOH gives a low yield of a mixture of o-and p-nitro phenols.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion and reason provided in the question, let's break down the statements step by step. ### Step 1: Analyze the Assertion **Assertion:** Nitrobenzene is used as a solvent in Friedel-Crafts reaction. - **Explanation:** Nitrobenzene is indeed used as a solvent in Friedel-Crafts reactions. This is because it can dissolve a variety of organic compounds and can withstand the reaction conditions typically used in Friedel-Crafts alkylation or acylation reactions. ### Step 2: Analyze the Reason **Reason:** Fusion of nitrobenzene with solid KOH gives a low yield of a mixture of o-and p-nitrophenols. - **Explanation:** When nitrobenzene is fused with solid potassium hydroxide (KOH), it undergoes a reaction that can lead to the formation of nitrophenols. However, the yield is low, and the product is a mixture of ortho (o-) and para (p-) nitrophenols. This is due to the steric and electronic factors involved in the reaction. ### Step 3: Evaluate the Relationship Between Assertion and Reason - Both the assertion and the reason are true statements. However, the reason does not directly explain why nitrobenzene is used as a solvent in Friedel-Crafts reactions. The reason discusses a different reaction involving nitrobenzene and KOH. ### Conclusion - **Final Answer:** The assertion is true, and the reason is also true, but the reason does not support the assertion. ---

To analyze the assertion and reason provided in the question, let's break down the statements step by step. ### Step 1: Analyze the Assertion **Assertion:** Nitrobenzene is used as a solvent in Friedel-Crafts reaction. - **Explanation:** Nitrobenzene is indeed used as a solvent in Friedel-Crafts reactions. This is because it can dissolve a variety of organic compounds and can withstand the reaction conditions typically used in Friedel-Crafts alkylation or acylation reactions. ### Step 2: Analyze the Reason ...
Promotional Banner

Topper's Solved these Questions

  • NITROGEN CONTAINING COMPOUNDS

    ERRORLESS |Exercise PROPERTIES OF NITROGEN CONTAINING COMPOUNDS|16 Videos
  • NITROGEN CONTAINING COMPOUNDS

    ERRORLESS |Exercise TESTS FOR NITROGEN CONTAINING COMPOUNDS|11 Videos
  • NITROGEN CONTAINING COMPOUNDS

    ERRORLESS |Exercise JEE (ADVANCED) 2018 MORE THAN ONE CHOICE CORRECT ANSWER|1 Videos
  • IONIC EQUILIBRIUM

    ERRORLESS |Exercise JS Jee Section (JEE Advanced (Numeric answer type question))|1 Videos
  • NUCLEAR CHEMISTRY

    ERRORLESS |Exercise JEE SECTION (Matrix Match Type Questions)|2 Videos

Similar Questions

Explore conceptually related problems

Assertion: Aniline does not undergo Friedel-Crafts reactions. Reason: -NH_2 group of aniline reacts with AlCl_3 to give acid-base reaction.

Assertion p-fluoro nitrobenzene is more reactive than p-bromo nitrobenzene in the aromatic necleophilic substitution reaction with acqueous NaOH Reason Addition of nuceophilie on the a-carbon of aryl halide is the rate determing step is S_(N)Ar reaction.

Alkylation of aromatic compounds with aliphatic compounds like halides in presence of Lewis acid catalyst is known as Friedel-Crafts alkylation. It is an exapmle of electrophilic substitution. In the process of acylation, R-overset(O)overset(||)C- group is introduced to the ring. Compounds having ( + mesomeric groups) like -NH_(2) do not give Friedel-Crafts reaction because these compounds undergo conjugation with the catalyst. In the alkylation process, most branched alkyl group is substituted because isomerisation of carbonium ion takes place. In some Friedel-Crafts reactions, the nature of product changes with the solvent used in the reaction. Predict whether the following statements are ture or false: Following compounds easily give Friedel-Crafts reaction: (a) True (b) False

Alkylation of aromatic compounds with aliphatic compounds like halides in presence of Lewis acid catalyst is known as Friedel-Crafts alkylation. It is an exapmle of electrophilic substitution. In the process of acylation, R-overset(O)overset(||)C- group is introduced to the ring. Compounds having ( + mesomeric groups) like -NH_(2) do not give Friedel-Crafts reaction because these compounds undergo conjugation with the catalyst. In the alkylation process, most branched alkyl group is substituted because isomerisation of carbonium ion takes place. In some Friedel-Crafts reactions, the nature of product changes with the solvent used in the reaction. Predict whether the following statements are ture or false: AlCl_(3) (aq.) is used as catalst in Frieded-Crafts reaction: (a) True (b) False

Alkylation of aromatic compounds with aliphatic compounds like halides in presence of Lewis acid catalyst is known as Friedel-Crafts alkylation. It is an exapmle of electrophilic substitution. In the process of acylation, R-overset(O)overset(||)C- group is introduced to the ring. Compounds having ( + mesomeric groups) like -NH_(2) do not give Friedel-Crafts reaction because these compounds undergo conjugation with the catalyst. In the alkylation process, most branched alkyl group is substituted because isomerisation of carbonium ion takes place. In some Friedel-Crafts reactions, the nature of product changes with the solvent used in the reaction. Predict whether the following statements are ture or false: Carbocations undergo isomerisation in Frieded-Crafts reaction. In each of the following alkyl halides the isomerisation takes place: CH_(3)-CH_(2)-CH_(2)-Cl , CH_(3)-CH_(2)-CH_(2)-CH_(2)-Cl (a) True (b) False

ERRORLESS -NITROGEN CONTAINING COMPOUNDS -PREPARATION OF NITROGEN CONTAINING COMPOUNDS
  1. Which of the following reaction does NOT occur ?

    Text Solution

    |

  2. Presently which reagent is used for separation of 1^(@),2^(@) and 3^(@...

    Text Solution

    |

  3. Which of the following compounds is an amino acid

    Text Solution

    |

  4. Rection of primary amines with aldehyde yields

    Text Solution

    |

  5. Assertion(A) : Aniline hydrogen sulphate on heating froms a mixture of...

    Text Solution

    |

  6. Assertion: Benzene diazonium chloride does not give tests for nitrogen...

    Text Solution

    |

  7. Assertion: Amines are basic in nature. Reason: Presence of ione pair...

    Text Solution

    |

  8. (A) p-O(2)N-C(6)H(4)COCH(3) is prepared by Friedel Crafts acylation of...

    Text Solution

    |

  9. Assertion : Alkyl isocyanides in acidified water give alkyl formamides...

    Text Solution

    |

  10. Assertion : Anilinium choride is more acidic than ammonium chloride. ...

    Text Solution

    |

  11. (A) Amines are more basic than esters and ethers. (R) Nitrogen is le...

    Text Solution

    |

  12. Assertion: Nitrobenzene is used as a solvent in Friedel-Craft's reacti...

    Text Solution

    |

  13. The electrolytic reduction of nitrobenzene in strongly acidic medium p...

    Text Solution

    |

  14. The reaction CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|...

    Text Solution

    |

  15. Consider the nitratio of benzene using mixed conc. H(2)SO(4) and HNO(3...

    Text Solution

    |

  16. The correct statement regarding the basicity of arylamines is .

    Text Solution

    |

  17. A given nitrogen-containing aromatic compound A reacts with Sn//HCl, f...

    Text Solution

    |

  18. Which one of the following nitro-compounds does not react with nitrous...

    Text Solution

    |

  19. Identify A and predict the type of reaction

    Text Solution

    |

  20. Nitration of aniline in strong acidic medium also gives m-nitroaniline...

    Text Solution

    |