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Oleum is considered as a solution of SO(...

Oleum is considered as a solution of `SO_(3)` in `H_(2)SO_(4)`, which is obtained by passing `SO_(3)` in solution of `H_(2)SO_(4)` When 100 g sample of oleum is diluted with desired mass of `H_(2)O` then the total mass of `H_(2)SO_(4)` obtained after dilution is known is known as % labelling in oleum.
For example, a oleum bottle labelled as '`019% H_(2)SO_(4)`' means the 109 g total mass of pure `H_(2)SO_(4)` will be formed when 100 g of oleum is diluted by 9 g of `H_(2)O` which combines with all the free `SO_(3)` present in oleum to form `H_(2)SO_(4)` as `SO_(3)+H_(2)O to H_(2)SO_(4)`
What is the % of free `SO_(3)` in an oleum that is labelled as `'104.5% H_(2)SO_(4)'` ?

A

`10`

B

`20`

C

`40`

D

none of these

Text Solution

Verified by Experts

The correct Answer is:
B
`%` free `SO_(3) = (4.5)/(18) xx 80 = 20`
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What is the percentage of free SO_(3) in an oleum sample that is labelled as '104.5% H_(2)SO_(4) ?

Calculate the % of free SO_(3) in an oleum, that is labelled 118%.

Knowledge Check

  • Oleum is considered as a solution of SO_(3) in H_(2)SO_(4) , which is obtained by passing SO_(3) in solution of H_(2)SO_(4) When 100 g sample of oleum is diluted with desired mass of H_(2)O then the total mass of H_(2)SO_(4) obtained after dilution is known is known as % labelling in oleum. For example, a oleum bottle labelled as ' 019% H_(2)SO_(4) ' means the 109 g total mass of pure H_(2)SO_(4) will be formed when 100 g of oleum is diluted by 9 g of H_(2)O which combines with all the free SO_(3) present in oleum to form H_(2)SO_(4) as SO_(3)+H_(2)O to H_(2)SO_(4) 9.0 g water is added into oleum sample lablled as "112%" H_(2)SO_(4) then the amount of free SO_(3) remaining in the solution is : (STP=1 atm and 273 K)

    A
    14.93 Lat STP
    B
    7.46 L at STP
    C
    3.73 L at STP
    D
    11.2 L at STP

  • Oleum is considered as a solution of SO_(3) in H_(2)SO_(4) , which is obtained by passing SO_(3) in solution of H_(2)SO_(4) When 100 g sample of oleum is diluted with desired mass of H_(2)O then the total mass of H_(2)SO_(4) obtained after dilution is known is known as % labelling in oleum. For example, a oleum bottle labelled as ' 019% H_(2)SO_(4) ' means the 109 g total mass of pure H_(2)SO_(4) will be formed when 100 g of oleum is diluted by 9 g of H_(2)O which combines with all the free SO_(3) present in oleum to form H_(2)SO_(4) as SO_(3)+H_(2)O to H_(2)SO_(4) If excess water is added into a bottle sample labelled as "112% H_(2)SO_(4) " and is reacted with 5.3 g NaCO_(3) then find the volume of CO_(2) evolved at 1 atm pressure and 300 K temperature after the completion of the reaction :

    A
    2.46 L
    B
    24.6 L
    C
    1.23 L
    D
    12.3 L

  • Oleum is considered as a solution of SO_(3) in H_(2)SO_(4) , which is obtained by passing SO_(3) in solution of H_(2)SO_(4) When 100 g sample of oleum is diluted with desired mass of H_(2)O then the total mass of H_(2)SO_(4) obtained after dilution is known is known as % labelling in oleum. For example, a oleum bottle labelled as ' 019% H_(2)SO_(4) ' means the 109 g total mass of pure H_(2)SO_(4) will be formed when 100 g of oleum is diluted by 9 g of H_(2)O which combines with all the free SO_(3) present in oleum to form H_(2)SO_(4) as SO_(3)+H_(2)O to H_(2)SO_(4) 1 g of oleum sample is diluted with water. The solution required 54 mL of 0.4 N NaOH for complete neutralization. The % free SO_(3) in the sample is :

    A
    74
    B
    26
    C
    20
    D
    None of these

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    Calculate the percent free SO_(3) in an oleum which is labelled '118% H_(2) SO_(4)' .

    What mass of H_(2)SO_(4) contains 32g oxygen ? .

    Comprehension # 7 Oleum is considered as a solution of SO_(3) in H_(2)SO_(4) , which is obtained by passing SO_(3) in solution of H_(2)SO_(4) . When 100g sample of oleum is diluted with desired weight of H_(2)O then the total mass of H_(2)SO_(4) obtained after dilution is known as % labelling in oleum. For example, a oleum bottle labelled as 109% H_(2)SO_(4) means the 109g total mass of pure H_(2)SO_(4) will be formed when 100g of oleum is diluted by 9g of H_(2)O which combines combines with all the free SO_(3) present in oleum to form H_(2)SO_(4) as SO_(3)+H_(2)OrarrH_(2)SO_(4) 9.0 g water is added into 100g oleum sample labelled as 112%H_(2)SO_(4) then the amount of free SO_(3) remaining in the solution is :

    Comprehension # 7 Oleum is considered as a solution of SO_(3) in H_(2)SO_(4) , which is obtained by passing SO_(3) in solution of H_(2)SO_(4) . When 100g sample of oleum is diluted with desired weight of H_(2)O then the total mass of H_(2)SO_(4) obtained after dilution is known as % labelling in oleum. For example, a oleum bottle labelled as 109% H_(2)SO_(4) means the 109g total mass of pure H_(2)SO_(4) will be formed when 100g of oleum is diluted by 9g of H_(2)O which combines combines with all the free SO_(3) present in oleum to form H_(2)SO_(4) as SO_(3)+H_(2)OrarrH_(2)SO_(4) If excess water is added into a bottle sample labelled as 112% H_(2)SO_(4) and is reacted with 5.3 g Na_(2)CO_(3) then find the volume of CO_(2) evloved at 1atm pressure and 300 K temperature after the completion of the reaction

    Comprehension # 7 Oleum is considered as a solution of SO_(3) in H_(2)SO_(4) , which is obtained by passing SO_(3) in solution of H_(2)SO_(4) . When 100g sample of oleum is diluted with desired weight of H_(2)O then the total mass of H_(2)SO_(4) obtained after dilution is known as % labelling in oleum. For example, a oleum bottle labelled as 109% H_(2)SO_(4) means the 109g total mass of pure H_(2)SO_(4) will be formed when 100g of oleum is diluted by 9g of H_(2)O which combines combines with all the free SO_(3) present in oleum to form H_(2)SO_(4) as SO_(3)+H_(2)OrarrH_(2)SO_(4) 1 g of oleum sample is diluted with water. The solution required 54 mL of 0.4 N NaOH for complete neutralization. The % of free SO_(3) in the sample is :

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