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In the production of quinoline this comp...

In the production of quinoline this compound is isolated from the reaction mixture by steam distillation. Calculate (a) at what temperature the mixture of water and quinoline will boil under a pressure of `740,mm Hg`. (b) What is the maximum number of grams of quinoline which can be distilled with `1000g` water vapour under this pressure.
The temperature dependence of vapour pressure.
The temprature dependence of vapour pressure of water and quionoline is given as follows :

Molecular weight of quinoline `=129`

Text Solution

Verified by Experts

The correct Answer is:
(a) 98.54`.

(a) This is an immiscible mixture of water and quinoline, so
`P_(1)^(@)+P_(2)^(@)=740`
By the help of table, we can say
`=98.5+((99-98.5))/((741.21727.95))xx(740-727.95)=98.54`.
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