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The vapour pressure of a solvent decreas...

The vapour pressure of a solvent decreased by `10 mm` of `Hg` when a non-volatile solute was added to the solvent. The mole fraction of solute is `0.2`, what would be the mole fraction of solvent if the decrease in vapour pressure is `20 mm` of `Hg`.

A

0.2

B

0.4

C

0.6

D

0.8

Text Solution

Verified by Experts

The correct Answer is:
C

`("P"_("solvent")^(0)-"P"_("solution"))/("P"_("solvent")^(0))="x"_("solute")`
`10/"P"_("solvent")^(0)=0.2`
`"P"_("solvent")`=50 mm Hg
Now again
`("P"_("solvent")^(0)-"P"_("solution"))/("P"_("solvent"))="x"_("solute")`
`20/50="x"_("solute")`
`"x"_("solute")=1-(2)/(5)=0.6`
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