Home
Class 11
CHEMISTRY
What is the value of Kp for the followin...

What is the value of `K_p` for the following reaction
`N_2(g)+2O_2(g) hArr N_2O_4(g)`
`{:("Reaction",K_p),(1/2N_2O_4(g)hArrNO_2(g),x),(1/2N_2(g)+O_2(g)hArrNO_2(g),y):}`

A

`y/x`

B

`y^2/x^2`

C

`x^2/y^2`

D

`xy^2`

Text Solution

AI Generated Solution

The correct Answer is:
To find the value of \( K_p \) for the reaction \[ N_2(g) + 2O_2(g) \rightleftharpoons N_2O_4(g) \] we will relate it to the two given reactions with their respective \( K_p \) values, \( x \) and \( y \). ### Step 1: Identify the given reactions and their \( K_p \) values - **Reaction 2**: \( \frac{1}{2} N_2O_4(g) \rightleftharpoons NO_2(g) \) with \( K_p = x \) - **Reaction 3**: \( \frac{1}{2} N_2(g) + O_2(g) \rightleftharpoons NO_2(g) \) with \( K_p = y \) ### Step 2: Manipulate the reactions to derive the desired reaction To derive the reaction \( N_2(g) + 2O_2(g) \rightleftharpoons N_2O_4(g) \), we can manipulate the given reactions as follows: 1. **Multiply Reaction 3 by 2**: \[ N_2(g) + 2O_2(g) \rightleftharpoons 2NO_2(g) \quad (K_p = y^2) \] 2. **Reverse Reaction 2**: \[ NO_2(g) \rightleftharpoons \frac{1}{2} N_2O_4(g) \quad (K_p = \frac{1}{x}) \] ### Step 3: Combine the manipulated reactions Now, we will add the modified Reaction 3 and the reversed Reaction 2: - From the modified Reaction 3, we have: \[ N_2(g) + 2O_2(g) \rightleftharpoons 2NO_2(g) \] - From the reversed Reaction 2, we have: \[ 2NO_2(g) \rightleftharpoons N_2O_4(g) \] Adding these two reactions gives: \[ N_2(g) + 2O_2(g) \rightleftharpoons N_2O_4(g) \] ### Step 4: Write the expression for \( K_p \) According to the rules of combining equilibrium constants: \[ K_p = K_p(\text{Reaction 3}) \times K_p(\text{Reversed Reaction 2}) \] Thus, \[ K_p = y^2 \times \frac{1}{x} = \frac{y^2}{x} \] ### Final Answer The value of \( K_p \) for the reaction \( N_2(g) + 2O_2(g) \rightleftharpoons N_2O_4(g) \) is: \[ K_p = \frac{y^2}{x} \] ---
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    GRB PUBLICATION|Exercise Reaction Quotient|10 Videos
  • CHEMICAL EQUILIBRIUM

    GRB PUBLICATION|Exercise Degree of Dissociation|39 Videos
  • ATOMIC STRUCTURE

    GRB PUBLICATION|Exercise Subjective Type|55 Videos
  • GASEOUS STATE

    GRB PUBLICATION|Exercise Exercise|530 Videos

Similar Questions

Explore conceptually related problems

Write the relation between k_p and K_c for the following reactions. (i) N_2(g) +3H_2(g) hArr 2NH_3(g) (ii) 2H_2O(g) hArr 2H_2(g) +O_2(g)

Explain the effect temperature on the endothermic reaction: N_2(g) +O_2(g) hArr 2NO(g)

K_(p)//K_(c) for the reaction CO(g)+1/2 O_(2)(g) hArr CO_(2)(g) is

Write the relationship between K_p and K_c for the reaction 2SO_2(g) +O_2(g) hArr 2SO_3(g)

Write the relation between K_(p)and K_(c) for the following reactions (i) N_(2)(g)+3H_(2)(g)hArr2H_(2)(g)+O_(2)(g) (ii) 2H_(2)O(g)hArr2H_(2)(g)+O_(2)(g)

For the first order reaction 2N_(2)O_(5)(g) rarr 4NO_(2)(g) + O_(2)(g)

GRB PUBLICATION-CHEMICAL EQUILIBRIUM-D.Le Chateliera principle
  1. What is the value of Kp for the following reaction N2(g)+2O2(g) hArr...

    Text Solution

    |

  2. For the reaction CO(g)+H2O(g) hArr CO2(g)+H2(g) at a given temperature...

    Text Solution

    |

  3. Given the following reaction at equilibium. N2(g) +3H2(g)hArr 2NH3(g...

    Text Solution

    |

  4. For an equilibrium H2O(s) hArr H2O(l)which of the following statements...

    Text Solution

    |

  5. When a bottle of cold drink is opened, the gas comes out with a fizzle...

    Text Solution

    |

  6. The equilibrium , SO2Cl2(g) hArr SO2(g)+Cl(2)(g) is attained at 25^@C ...

    Text Solution

    |

  7. An equilibrium mixture in a vessel of capacity 100 litre contains 1 mo...

    Text Solution

    |

  8. The following two reactions: i. PCl(5)(g) hArr PCl(3)(g)+Cl(2)(g) ...

    Text Solution

    |

  9. For the reaction, 4NH(3)(g) + 5O(2)(g)hArr4NO(g) + 6 H(2)O(l), Delt...

    Text Solution

    |

  10. For the reaction H(2)(g)+I(2)(g) hArr 2HI(g) The equilibrium const...

    Text Solution

    |

  11. To the system, LaCl(3)(s)+H(2)O(g) hArr LaClO(s)+2HCL(g)-"Heat" alre...

    Text Solution

    |

  12. In the Haber process for the industrial manufacturing of ammonia invol...

    Text Solution

    |

  13. For the reaction CaCO3(s)hArr CaO(s)+CO2(g) , the pressure of CO2 (g) ...

    Text Solution

    |

  14. Which of the following will not shift the equilibrium , N2+3H2 hArr 2N...

    Text Solution

    |

  15. One mole of helium (He) gas is added to the equilibrium N2O4(g) hArr 2...

    Text Solution

    |

  16. Some quantity of water is contained in a container as shown in figure....

    Text Solution

    |

  17. For the equilibrium CuSO(4)xx5H(2)O(s)hArrCuSO(4)xx3H(2)O(s) + 2H(2)O(...

    Text Solution

    |