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Why is the extractio of Cu from pyrites ...

Why is the extractio of Cu from pyrites more difficult than that from its oxide ore through reduction?

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The standard free energy `(Delta_(f)G^(@))` of formation of `Cu_(2)S` is more negative than those of `CS_(2)` and `H_(2)S`.
Therefore, carbon or hydrogen cannot reduce `Cu_(2)S` to `Cu`

On the other hand, `(Delta_(f)G^(@))` of `Cu_(2)O` is less `-ve` than that of `CO.` Hence, carbon can easily reduce `Cu_(2)O` to `Cu.`
`Cu_(2)O(s)+C(s) rarr 2Cu(s)+CO(g)`
Therefore, the extraction of copper from pyrites is more difficult than that from its oxide ore, through reduction.
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CHHAYA PUBLICATION-GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS-NCERT EXERCISE QUESTIONS
  1. Copper can be extracted by hydrometallurgy but not zinc. Explain.

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  2. What is the role of depressant in froth-floatation process?

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  3. Why is the extractio of Cu from pyrites more difficult than that from ...

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  4. Explain (i) Zone refining

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  5. Explain (ii) Column chromatography.

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  6. Out of C and CO, which is better reducing agent at 673K ?

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  7. Name the common elements present in the anode mud in electrolytic refi...

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  8. Write the reactions taking place in different zones in the blast furna...

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  9. Write chemical reactions taking place in the extraction of zinc from z...

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  10. State the role of silica in the metallurgy of copper.

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  11. What is meant by the term, chromatography?

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  12. What criterion is followed for the selection of the stationary phase i...

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  13. Describe a method for refining nickel.

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  14. How can you separate alumina from silica in a bauxite ore associated w...

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  15. Giving examples, differentiate between roasting and calcination.

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  16. How is cast iron different from pig iron?

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  17. Why copper matte is put in silica lined converter?

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  18. Differentiate between minerals and ores.

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  19. What is the role of cryolite in the metallurgy of aluminium?

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  20. How is leaching carried out in case of low grade Cu ores ?

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