Pure `PCl_(5) ` is introduced into an evacaated chamber and to equilibrium at `247^(@)C` and 2.0 atm .The equilibrium gases mixure contains 40% choririne by volume . Calculate `K_(p)` at `247^(@)C` for the reaction `PCl_(5)(g)hArrPCl_(3)(G)+Cl_(2)(g)`
A
`0.625` atm
B
`4 atm`
C
`1.6 atm`
D
none of these
Text Solution
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The correct Answer is:
c
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For the reaction, PCl_(5)(g)to PCl_(3)(g)+Cl_(2)(g)
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Pure PCl_(5)(g) was introduced into an evacuated vessel and comes to equilibrium at 24^(@)C and 2 atm pressure. At equilibrium mixture contains 40% by volume of Cl_(2)(g) PCl_(5)(g)hArr(PCl_(3)(g)+Cl_(2)(g) Which of the following statement(s) regarding the above equilibrium is/are correct?
For PCl_(5)(g)hArrPCl_(3)(g)+Cl_(2)(g), write the expression of K_(c)