Variation of equilibrium constan K with temperature is given by van't Hoff equation `InK=(Delta_(r)S^(@))/R-(Delta_(r)H^(@))/(RT)` for this equation, `(Delta_(r)H^(@))` can be evaluated if equilibrium constans `K_(1)` and `K_(2)` at two temperature `T_(1)` and `T_(2)` are known. `log(K_(2)/K_(1))=(Delta_(r)H^(@))/(2.303R)[1/T_(1)-1/T_(2)]` Select the correct statement :
A
Value of `K_(eq)` always increases with increasing temperature
B
For expthermic reaction of value of `K_(eq)` increases with decreasing in temperature
C
For endothermic reaction value of `K_(eq)` increases with decreasihng in temperature
D
For exothermic reactionslope is `(logK Vs.1//T)` negative
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Variation of equilibrium constan K with temperature is given by van't Hoff equation InK=(Delta_(r)S^(@))/R-(Delta_(r)H^(@))/(RT) for this equation, (Delta_(r)H^(@)) can be evaluated if equilibrium constans K_(1) and K_(2) at two temperature T_(1) and T_(2) are known. log(K_(2)/K_(1))=(Delta_(r)H^(@))/(2.303R)[1/T_(1)-1/T_(2)] For an isomerization X(g)hArrY(g) the temperature dependency of equilibrium cohnstant is given by : lnK=2-(1000)/T The value of Delta_(r)S^(@) at 300 K is :
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