Home
Class 12
CHEMISTRY
What is Z in the following sequence of r...

What is Z in the following sequence of reactions?
`Z overset(PCl_(3))toX overset(alc.KOH)to Y underset((ii)H_(2)O boil)overset((i)Conc.H_(2)SO_(4))toZ`

A

`H_(2)C=CH-CH_(2)-OH`

B

`CH_(3)CHOHCH_(3)`

C

`(CH_(3)CH_(2))COOH`

D

`CH_(3)CH=CH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine what Z is in the given sequence of reactions, let's analyze each step systematically. ### Step 1: Identify the starting compound Z We need to identify the starting compound Z, which is transformed through a series of reactions and eventually returns to the same compound Z. ### Step 2: Reaction with PCl3 The first reaction involves Z being treated with PCl3. This suggests that Z is likely an alcohol since PCl3 is commonly used to convert alcohols into alkyl chlorides. Let’s assume Z is isopropyl alcohol (CH3-CHOH-CH3). When isopropyl alcohol reacts with PCl3, it forms isopropyl chloride (CH3-CHCl-CH3). ### Step 3: Reaction with alcoholic KOH Next, the product (isopropyl chloride) undergoes a reaction with alcoholic KOH. This reaction typically leads to an elimination reaction, where a hydrogen atom and a chlorine atom are removed, resulting in the formation of an alkene. For isopropyl chloride, the elimination reaction would yield propene (CH3-CH=CH2). ### Step 4: Reaction with concentrated H2SO4 The propene then reacts with concentrated H2SO4. In this step, the alkene undergoes protonation to form a carbocation. The more stable secondary carbocation (CH3-CH+-CH3) is formed. ### Step 5: Reaction with water After the formation of the carbocation, water acts as a nucleophile and attacks the positively charged carbon, leading to the formation of an oxonium ion (CH3-CHOH-CH3+). ### Step 6: Deprotonation Finally, deprotonation occurs, where the oxonium ion loses a proton to regenerate isopropyl alcohol (Z). ### Conclusion After analyzing the sequence of reactions, we can conclude that the compound Z is isopropyl alcohol (CH3-CHOH-CH3). ### Final Answer Z = Isopropyl alcohol (CH3-CHOH-CH3) ---
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS AND ETHERS

    GRB PUBLICATION|Exercise EXERCISE 49|1 Videos
  • ALCOHOLS AND ETHERS

    GRB PUBLICATION|Exercise EXERCISE 50|1 Videos
  • ALCOHOLS AND ETHERS

    GRB PUBLICATION|Exercise EXERCISE 47|1 Videos
  • ALCOHOL, ETHER AND EPOXY

    GRB PUBLICATION|Exercise STRAIGHT OBJECTIVE TYPE|22 Videos
  • BIOMOLECULES, POLYMERS, PRACTICAL ORGANIC CHEMISTRY AND CHEMISTRY IN DAILY LIFE

    GRB PUBLICATION|Exercise SUBJECTIVE TYPE|40 Videos

Similar Questions

Explore conceptually related problems

In the sequence of reaction , identify (Z). CH_3CH_2CH_2OH overset(PCl_3)to X overset(alc. KOH)to Y underset(H_2O,"boil")overset("Conc."H_2SO_4)to Z