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In the reaction: Me(3)C-O-CH(2)CH(3)+...

In the reaction:
`Me_(3)C-O-CH_(2)CH_(3)+underset("1 mole")(HI) overset(Delta)to`

A

`Me_(3)C-OH+CH_(3)CH_(2)I`

B

`Me_(3)C-I+CH_(3)CH_(2)OH`

C

`Me_(3)C-I+CH_(3)CH_(2)I`

D

`Me_(3)C-OH+CH_(3)CH_(2)OH`

Text Solution

Verified by Experts

The correct Answer is:
B
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Complete the following reactions: (i) CH_(3)-overset(CH_(3))overset(|)underset(Cl)underset(|)C-CH_(2)CH_(3) overset("alc"KOH) underset(Delta) to A overset(O_(3))underset(Zn//H_(2)O) to (B+C) (ii) CH_(3)overset(I)CH-CH_(3)overset("alc"KCN) to A underset((ii)H_(2)O.OH.H_(2)O_(2))overset((i)SnCl_(2)//HCl) to B (iii) HCN overset(HCl//AlCl_(3)) to A underset((ii) (H_(2)O)//H^(-))overset((i)C_(6)H_(6)Delta) to B (iv)

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Knowledge Check

  • In the reaction (CH_(3))_(3)C-O-CH_(2)CH_(3)+underset((1"mole"))(HI)overset(heat)(rarr) the products formed is (are)

    A
    `(CH_(3))_(3)COH and CH_(3)CH_(2)l`
    B
    `(CH_(3))_(3)Cl and CH_(3)CH_(2)I`
    C
    `(CH_(3))_(3)CI and CH_(3)CH_(2)OH`
    D
    `(CH_(3))_(3)C-underset(H)underset(|)overset(+)(O)-CH_(2)CH_(2)CH_(3)I^(-)`

  • The elimination reaction {:(CH_(3)-CH_(2).CH-CH_(3)),(" |"),(" ".^(o+)N Me_(3) overset(Delta)rarrunderset("major")(CH_(3)CH_(2)-CH = CH_(2))):} is governed by

    A
    The Saytzeff rule
    B
    The Hofmann rule
    C
    The Saytzeff as well as the Hofmann rule
    D
    None of these

  • In the reaction CH_(3)-C-=C-CH_(3)underset((ii)H_(2)//Zn)overset((i)X)(to)CH_(3)-underset(O)underset(||)(C)-underset(O)underset(||)(C)-CH_(3) X is:

    A
    `HNO_(3)`
    B
    `O_(2)`
    C
    `O_(3)`
    D
    `KMnO_(4)`

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