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Which one of the following has the corre...

Which one of the following has the correct order of `Delta_(o)` ?

A

`[Co(CN)_(6)]^(3-) gt [Co(H_(2)O)_(6)]^(3+)`

B

`[Co(H_(2)O)_(6)]^(2+) lt [Co(H_(2)O)_(6)]^(3+)`

C

`[Co(H_(2)O)_(6)]^(3+) gt [Rh(H_(2)O)_(6)]^(3+)`

D

`[Co(NH_(3))_(6)]^(3+) lt [CoF_(6)]^(3-)`

Text Solution

Verified by Experts

(A,B)
(A) `Delta _(o)prop` strength of ligand. `CN^(-)` is stronger field ligand than `H_(2)O.So Delta_(o)` of `[Co(CN)_(6)]^(3-) gt [Co(H_(2)O)_(6)]^(2+) [Co(CN_(6))]^(3)`
(B) `Delta_(o)prop` oxidation state of central metal ion. So `Delta_(o)` of `[Co(H_(2)O)_(6)]^(2+) lt [Co(H_(2)O)_(6)]^(3+)`
Note : `Delta_(o)prop` principal quantum number of central atom/ion i.e.n.
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