Home
Class 12
CHEMISTRY
A compund reacts with CHCl(3) and KOH gi...

A compund reacts with `CHCl_(3)` and `KOH` gives offensive smelling compound `A`. `'A'` can be

A

Primary aliphatic amine

B

Primary aromatic amine

C

`2^(@)` amine

D

Tertiary amine

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the compound 'A' that is formed when a primary amine reacts with chloroform (CHCl₃) and potassium hydroxide (KOH). The reaction is known as the "Hofmann degradation" or "Hofmann reaction," which typically involves the formation of isocyanide (also known as carbylamine) from primary amines. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are chloroform (CHCl₃) and potassium hydroxide (KOH), which are used in the reaction with a primary amine. 2. **Understand the Reaction**: - When a primary amine (RNH₂) reacts with chloroform and KOH, it undergoes a reaction to form an isocyanide (RNC), which is the offensive-smelling compound 'A'. 3. **Write the Reaction**: - The general reaction can be represented as: \[ RNH_2 + CHCl_3 + 3KOH \rightarrow RNC + 3KCl + 3H_2O \] - Here, R represents the alkyl or aryl group attached to the amine. 4. **Identify the Product**: - The product formed, isocyanide (RNC), is known for its offensive smell, which confirms that 'A' is indeed isocyanide. 5. **Conclusion**: - Therefore, the offensive-smelling compound 'A' that is formed from the reaction of a primary amine with chloroform and KOH is an isocyanide. ### Final Answer: The offensive-smelling compound 'A' is an isocyanide (RNC).

To solve the problem, we need to identify the compound 'A' that is formed when a primary amine reacts with chloroform (CHCl₃) and potassium hydroxide (KOH). The reaction is known as the "Hofmann degradation" or "Hofmann reaction," which typically involves the formation of isocyanide (also known as carbylamine) from primary amines. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are chloroform (CHCl₃) and potassium hydroxide (KOH), which are used in the reaction with a primary amine. 2. **Understand the Reaction**: ...
Promotional Banner

Topper's Solved these Questions

  • PRACTICAL ORGANIC CHEMISTRY

    NARAYNA|Exercise SCQ_TYPE|47 Videos
  • PRACTICAL ORGANIC CHEMISTRY

    NARAYNA|Exercise COMPREHENSION_TYPE|18 Videos
  • PRACTICAL ORGANIC CHEMISTRY

    NARAYNA|Exercise MATCH THE COLUMN|8 Videos
  • POLYMERS

    NARAYNA|Exercise EXERCISE -4|8 Videos
  • QUALITATIVE ANALYSIS

    NARAYNA|Exercise Subjective Type Question|33 Videos

Similar Questions

Explore conceptually related problems

An organic compound A with molecular formula C_2H_7N produces a compound B which on reaction with HNO_2 gives ethyl alcohol and when warmed with CHCl_3 and alcoholic KOH, an offensive smelling compound C is produced. C is

An orgnic compound (A) on reduction gave a compound (B). Upon treatment with HNO_(2) ,(B) gave ethyl alcohol and on warming with CHCI_(3) , and alcoholic KOH, (b) gave offensive smell. The compound (A) is:

An aromatic compound A on heating with Br, and KOH forms a compound B of molecular formula CHN which on reacting with CHCI and alcoholic KOH produces a foul smelling compound C. Write the structures and IUPAC names of compounds A, B and C.

An organic compound 'A' having molecular formula C_(2)H_(3)N on reduction gave another compound 'B' Upon treatment with nitrous acid, 'B' gave ethyl alcohol on warming with chloroform and alcoholic KOH, it formed an offensive smelling compound 'C'. The compound 'C' is :

NARAYNA-PRACTICAL ORGANIC CHEMISTRY-MCQ_TYPE
  1. An organic compound has the structure It will give

    Text Solution

    |

  2. The most reactive among the following pairs towards NaOH is

    Text Solution

    |

  3. CH(3)-overset(O)overset(||)(C)-C(2)H(5) & CH(3)-overset(O)overset(||)(...

    Text Solution

    |

  4. Which of the these can be distinguished by adding HCl or Na(2)CO(3)?

    Text Solution

    |

  5. Which of the following reactions occur during the detection of nitorge...

    Text Solution

    |

  6. A compund reacts with CHCl(3) and KOH gives offensive smelling compoun...

    Text Solution

    |

  7. HCOOH and HCHO may be distinguished by

    Text Solution

    |

  8. Benzaldehyde and CH(3)COCl can be distinguished by

    Text Solution

    |

  9. Acetic acid and CH(3)COCl can be distinguished by

    Text Solution

    |

  10. An organic compund contains 52% carbon. If could be

    Text Solution

    |

  11. Which of the following will evolve CO(2) on reaction with NaHCO(3)?

    Text Solution

    |

  12. Which of the following wil give benzoic acid on acidic hydrolysis?

    Text Solution

    |

  13. Which of the following does not give brick red ppt. with Fehling solut...

    Text Solution

    |

  14. Which of the following compounds can be purified by steam distillation...

    Text Solution

    |

  15. Which of the following compounds can be purified by vaccum distillatio...

    Text Solution

    |

  16. Chromatography technique is used in the separation of:

    Text Solution

    |

  17. Mixed melting point of an organic compound is determine to

    Text Solution

    |

  18. Compound 'P'(C(10)H(12)O) evolves H(2) gas with Na metal. It reaches w...

    Text Solution

    |

  19. Compound (X)C(9)H(10)O in inert to Br(2)//"CC"l(4). Vigorous oxidation...

    Text Solution

    |

  20. Which is/are the correct method for separatig a mixture of benzoic aci...

    Text Solution

    |