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Why is nitric acid added to sodium extra...

Why is nitric acid added to sodium extract before adding silver nitrate for testing halogens?

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While testing the Lassaigne’s extract for the presence of halogens, it is first boiled with dilute nitric acid. This is done to decompose NaCN to HCN and `Na_(2)S` to `H_(2)S` and to expel these gases. That is, if any nitrogen and sulphur are present in the form of NaCN and `Na_(2)S`, then they are removed. The chemical equations involved in the reaction are represented as
`NaCN+HNO_(3)toNaNO_(3)+HCN`
`Na_(2)S+2HNO_(3)to2NaNO_(3)+H_(2)S`
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NCERT-ORGANIC CHEMISTRY- SOME BASIC PRINCIPLES AND TECHNIQUES-EXERCISE
  1. Discuss the chemistry of Lassaigne’s test.

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  2. Differentiate between the principle of estimation of nitrogen in an or...

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  3. Discuss the principle of estimation of halogens, sulphur and phosphoru...

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  4. Explain the principle of paper chromatography.

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  5. Why is nitric acid added to sodium extract before adding silver nitrat...

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  6. Explain the reason for the fusion of an organic compound with metallic...

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  7. Name a suitable technique of the components from a mixture of calcium ...

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  8. Explain why an organic liquid vaporises at a temperature below its boi...

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  9. Will C Cl4 give white precipitate of AgCl on heating with nitrate? Giv...

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  10. Why is solution of potassium hydroxide used to absorb carbon dioxide e...

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  11. Why is it necessary to use acetic acid and not suplhuric acid for the ...

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  12. An organic compound contains 69% carbon and 4.8% hydrogen, the remaind...

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  13. 0.50 gm of an organic compound was treated according to Kjeldahl's meg...

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  14. 0.3080 gm of and organic chloro compound gave 0.5740 gm of siver chlor...

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  15. In the estimation of sulphur by carius method, 0.468 gm of an organic ...

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  16. In the organic compound CH(2) = CH – CH(2) – CH(2) – C equivCH, the pa...

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  17. In the Lassaigne’s test for nitrogen in an organic compound, the Pruss...

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  18. Which of the following carbocation is most stable ? (a) (CH(3))(3)C....

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  19. For the purification of organic compounds, the latest technique follow...

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  20. The reaction: CH(3)CH(2)I + KOH(aq)toCH(3)CH(2)OH+KI is classified...

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