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CH(3)-.^(2)underset(.(1)CH(2)-H)underset...

`CH_(3)-.^(2)underset(._(1)CH_(2)-H)underset(|)overset(H)overset(|)C-.^(3)overset(H)overset(|)CH-._(4)CH_(2)-H,
`C_(1)-H,C_(2)-H,C_(3)-H`and `C_(4)-H` the homolytic bond dissociation energy is in the order :

A

`C_(2)-HgtC_(3)-HgtC_(4)-HgtC_(1)-H`

B

`C_(1)-HgtC_(4)-HgtC_(2)-HgtC_(3)-H`

C

`C_(2)-HgtC_(3)-HgtC_(1)-HgtC_(4)-H`

D

`C_(1)-HgtC_(4)-HgtC_(3)-HgtC_(2)-H`

Text Solution

Verified by Experts

The correct Answer is:
D

Bond dissocation energy can be decided by comparing stability of free radical.
`C_(2)-H` has minimum BDE as this produces highly stabilise free radical.
`H_(3)O-underset(CH_(3))underset(|)C-CH_(2)-CH_(3)`
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HIMANSHU PANDEY-GENERAL ORGANIC CHEMISTRY-Level 2 (Q.26 To Q.50)
  1. CH(3)-.^(2)underset(.(1)CH(2)-H)underset(|)overset(H)overset(|)C-.^(3)...

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  2. Which of the following has longest C-O bond?

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  3. In which of the following molecules pi-electron density in ring is max...

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  4. The correct stability order of the following resonance structures is :...

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  5. What is correct increasing oreder of bond lengths of bond indicated as...

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  6. Acylium cation has two resonating sturctures (I) and (II), R-underse...

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  7. Consider the following three amines, (1) CH(3)CH(2)-overset(* *)NH(2...

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  8. The C-Cl bond length is shortest in :

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  9. Which of the following pairs of structure are resonance structure?

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  10. Which of the following is pair of resonance structure?

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  11. The most stable diene is :

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  12. Which of the following cation would have greatest stability?

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  13. Which of the following is not valid resonance structre of polyene?

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  14. Most contributing structure in introethene is :

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  15. The most stable resonating structure of CH(3)-underset(* *)overset(* ...

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  16. Which of the following does not represent structure of ?

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  17. The correct stability order of following species is :

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  18. Choose the correct staement :

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  19. Which carbocation is most stabilised among following?

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  20. Which of the following cations is most stable?

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