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Which one of the followng is square plan...

Which one of the followng is square planar in structure and has diamagnetic property ?

A

`[Ni (H_(2)O)_(6)]^(2+)`

B

`[Ni (CO)_(4)]`

C

`[Ni(CN)_(4)]^(2-)`

D

`p[NiCl_(4)]^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
C

`[Ni(CN)_(4)]^(2-)` have `CN^(-)` as stong field ligand which helps in pairing of electron thus 2 unpaired electrons of nickle are paired up due to which the coordinated ion is diamagnetic with `dsp^(2)` hybridisation and square planar geometry.
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