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According to the first law of thermodyna...

According to the first law of thermodynamics, `DeltaU=q+w`. Write down the form of this equation for the following process: (i) cyclic process (ii) adiabatic process (iii) isothermal expansion of an ideal gas (iv) process occurring in an isolated system.

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(iv) An isolated systemm does not exchange energy or matter with its surroundings. So, for a process occuring in an isolated system, q=0 and w=0. therefore, `DeltaU=q+w` or, `DeltaU=0+0` or, `DeltaU=0`.
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CHHAYA PUBLICATION-CHEMICAL THERMODYNAMICS-WARM UP EXERCISE
  1. Why does the total energy of an isolated system remains constant?

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  2. Write down the mathematical form of the first law of thermodynamics fo...

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  3. According to the first law of thermodynamics, DeltaU=q+w. Write down t...

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  4. Among the following processes identify those in which the change in in...

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  5. A closed system undergoes a process AtoB. If it occurs reversible, the...

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  6. For an ideal gas, the isothermal free expansion and adiabatic free exp...

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  7. For chemical changes, why is the change in enthalpy more useful than t...

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  8. From the equation H=W+PV, explain what H is a state function.

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  9. From the definition of enthalpy show that for n mol of an ideal gas H=...

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  10. Prove that for an ideal gas undergoing an isothermal change, DeltaH=0.

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  11. Under what conditions are (i) DeltaU=q(V)& (ii) DeltaH=q(P) ?

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  12. Why is the heat capacity a path-dependent quantity?

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  13. Heat required to raise the temperatuer of 1 mol of a gas by 1^(@)C is ...

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  14. Why is the molar heat capacity at constant pressure greater than that ...

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  15. c(P)-c(V)=xJ*g^(-1)*K^(-1) and C(P,m)-C(V,m)=Xj*mol^(-1)*K^(-1) for an...

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  16. Why is the sign of DeltaH negative for an exothermic reaction and why ...

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  17. A 0.5 mol sample of H(2)(g) reacts with a 0.5 mol sample of Cl(2)(g) t...

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  18. A 1 mol sample of N(2)(g) reacts with 1 mol of O(2)(g) to form 2 mol o...

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  19. Identify the exothermic and endothermic changes: (i) NO(g)+(1)/(2)O(...

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  20. Write down the thermochemical equations for the following reactions: ...

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