Home
Class 12
CHEMISTRY
P - nitrophenol is more acidic than phen...

P - nitrophenol is more acidic than phenol. Explain.

Text Solution

Verified by Experts

In p - nitrophenol, the electron - attracting - `NO_(2)` group by its stronger -R effect and relatively weaker -I effect more positively polarised compared to the oxygen atom of phenol. As a result, the O - H bond in p nitrophenol dissociates more easily to give `H^(oplus)` ions. For this reason, p - nitrophenol is more acidic than phenol.
Promotional Banner

Topper's Solved these Questions

  • ORGANIC CHEMISTRY : BASIC PRINCIPLES AND TECHNIQUES

    CHHAYA PUBLICATION|Exercise ENTRANCE QUESTION BANK (WBJEE)|1 Videos
  • ORGANIC CHEMISTRY : BASIC PRINCIPLES AND TECHNIQUES

    CHHAYA PUBLICATION|Exercise ENTRANCE QUESTION BANK|97 Videos
  • ORGANIC CHEMISTRY : BASIC PRINCIPLES AND TECHNIQUES

    CHHAYA PUBLICATION|Exercise SLOVED NCERT EXERCISE|38 Videos
  • MODEL QUESTIONS PAPER

    CHHAYA PUBLICATION|Exercise SET III (SECTION II) (GROUP D )|12 Videos
  • P-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise PRACTICE SET 7 (ANSWER THE FOLLOWING QUESTIONS) : -|17 Videos

Similar Questions

Explore conceptually related problems

Assertion (A) p-nitrophenol is more acidic than phenol. Reason (R) Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.

Give reason for the following: (a) p-nitrophenol is more acidic than o-nitrophenol. (b) Phenol is more reactive towards electrophilic substitution reaction than benzene.

Phenol is a stronger acid than alcohol. Explain

Acidiccharacter of 4-nitrophenol is greater than 3-nitrophenol Explain why? Compare basic character of aromatic and aliphatic amines.

Chloroform is more acidic than fluoroform. Explain.

Account for the following : Ortho nitrophenol is volatile than para nitrophenol explain.

Why 2-chloroethanol is more acidic than ethanol ?

Why 2-chloroethanol is more acidic than ethanol ?

CHHAYA PUBLICATION-ORGANIC CHEMISTRY : BASIC PRINCIPLES AND TECHNIQUES -HIGHER ORDER THINKING SKILL (HOTS) QUESTION
  1. (1) Give structure and IUPAC name of an optically active alkane having...

    Text Solution

    |

  2. The following two isomers may be called diastereoisomers but not enant...

    Text Solution

    |

  3. P - nitrophenol is more acidic than phenol. Explain.

    Text Solution

    |

  4. P - nitroanilin is a weaker base than aniline. Explain.

    Text Solution

    |

  5. Dipole moment of vinyl chloride (CH(2) = CHCI) is less than the dipole...

    Text Solution

    |

  6. Arrange the following ions in order of increasing basicity and explain...

    Text Solution

    |

  7. Give example: (1) a non - nuclephilic anion (2) a planar carbocati...

    Text Solution

    |

  8. Explain the given basicity order in aqueous medium: (CH(3))(2)overse...

    Text Solution

    |

  9. Which of the two: O(2)NCH(2)CH(2)O^(Theta)orCH(3)CH(2)O^(Theta) is exp...

    Text Solution

    |

  10. CH(3)CI undergoes hydrolysis more easily than C(6)H(5)CI. Explain.

    Text Solution

    |

  11. Benzyl chloride participates in S(N)1 reaction even through it is a pr...

    Text Solution

    |

  12. Bond dissociation enthalpy of C(6)H(5)CH(2) - H bond is much less than...

    Text Solution

    |

  13. N,N,2,6 - Tetramethylaniline is more basic than N,N - dimethylaniline....

    Text Solution

    |

  14. Chloroform is more acidic than fluoroform. Explain.

    Text Solution

    |

  15. How can you separate benzoic acid and nitro benzene from their mixture...

    Text Solution

    |

  16. How will you separate benzyl alcohol (neutral) and phenol (acidic) fro...

    Text Solution

    |

  17. Why is impure glycerol purified by distillation under reduced pressure...

    Text Solution

    |

  18. Why is it necessary to use acetic acid and not sulphuric acid for acid...

    Text Solution

    |

  19. Preence of N is hydroxylamine hydrochloride cannot be detected by Lass...

    Text Solution

    |

  20. How can it be possible to detect the presence of nitrogen in hydrazin...

    Text Solution

    |