Home
Class 12
CHEMISTRY
Chloroform is more acidic than fluorofor...

Chloroform is more acidic than fluoroform. Explain.

Text Solution

Verified by Experts

`CF_(3)^(Theta)`, the conjugate base of fluroform `(CHF_(3))`, is stabilised by - I effect of 3 F - atoms. But `C CI_(3)^(Theta)` , the conjugate base of chloroform `(CHCI_(3))`, is relatively more stabilised by somewhat weaker - I effect of 3 - CI - atoms along with d - orbital resonance (CI has vacant d - orbital). So chloroform is more acidic than fluroform.
Promotional Banner

Topper's Solved these Questions

  • ORGANIC CHEMISTRY : BASIC PRINCIPLES AND TECHNIQUES

    CHHAYA PUBLICATION|Exercise ENTRANCE QUESTION BANK (WBJEE)|1 Videos
  • ORGANIC CHEMISTRY : BASIC PRINCIPLES AND TECHNIQUES

    CHHAYA PUBLICATION|Exercise ENTRANCE QUESTION BANK|97 Videos
  • ORGANIC CHEMISTRY : BASIC PRINCIPLES AND TECHNIQUES

    CHHAYA PUBLICATION|Exercise SLOVED NCERT EXERCISE|38 Videos
  • MODEL QUESTIONS PAPER

    CHHAYA PUBLICATION|Exercise SET III (SECTION II) (GROUP D )|12 Videos
  • P-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise PRACTICE SET 7 (ANSWER THE FOLLOWING QUESTIONS) : -|17 Videos

Similar Questions

Explore conceptually related problems

P - nitrophenol is more acidic than phenol. Explain.

Phenol is a stronger acid than alcohol. Explain

HF is weaker acid than HI. Explain.

Is boric acid a protonic acid? Explain.

Aliphatic primary amine is more basic than aniline. Explain with reason.

Is boric acid a protonic acid ? Explain.

Explain why 2 - fluorobutanoic acid is more acidic than 2 - chlorobutanoic acid.

BF_3 is a weaker Lewis acid than BCl_3 , even though F is more electronegative than Cl. Explain.

CHHAYA PUBLICATION-ORGANIC CHEMISTRY : BASIC PRINCIPLES AND TECHNIQUES -HIGHER ORDER THINKING SKILL (HOTS) QUESTION
  1. (1) Give structure and IUPAC name of an optically active alkane having...

    Text Solution

    |

  2. The following two isomers may be called diastereoisomers but not enant...

    Text Solution

    |

  3. P - nitrophenol is more acidic than phenol. Explain.

    Text Solution

    |

  4. P - nitroanilin is a weaker base than aniline. Explain.

    Text Solution

    |

  5. Dipole moment of vinyl chloride (CH(2) = CHCI) is less than the dipole...

    Text Solution

    |

  6. Arrange the following ions in order of increasing basicity and explain...

    Text Solution

    |

  7. Give example: (1) a non - nuclephilic anion (2) a planar carbocati...

    Text Solution

    |

  8. Explain the given basicity order in aqueous medium: (CH(3))(2)overse...

    Text Solution

    |

  9. Which of the two: O(2)NCH(2)CH(2)O^(Theta)orCH(3)CH(2)O^(Theta) is exp...

    Text Solution

    |

  10. CH(3)CI undergoes hydrolysis more easily than C(6)H(5)CI. Explain.

    Text Solution

    |

  11. Benzyl chloride participates in S(N)1 reaction even through it is a pr...

    Text Solution

    |

  12. Bond dissociation enthalpy of C(6)H(5)CH(2) - H bond is much less than...

    Text Solution

    |

  13. N,N,2,6 - Tetramethylaniline is more basic than N,N - dimethylaniline....

    Text Solution

    |

  14. Chloroform is more acidic than fluoroform. Explain.

    Text Solution

    |

  15. How can you separate benzoic acid and nitro benzene from their mixture...

    Text Solution

    |

  16. How will you separate benzyl alcohol (neutral) and phenol (acidic) fro...

    Text Solution

    |

  17. Why is impure glycerol purified by distillation under reduced pressure...

    Text Solution

    |

  18. Why is it necessary to use acetic acid and not sulphuric acid for acid...

    Text Solution

    |

  19. Preence of N is hydroxylamine hydrochloride cannot be detected by Lass...

    Text Solution

    |

  20. How can it be possible to detect the presence of nitrogen in hydrazin...

    Text Solution

    |