Home
Class 12
CHEMISTRY
How will you prove: acidic character o...

How will you prove:
acidic character of acetylene.

Text Solution

Verified by Experts

When acetylene is added to water and shaken ,the resulting solution does turn blue litmus red. The following reactions in which the H-atoms of acetylene are replaced by metal atom prove the acidic character of acetylene.
(a) Acetylene `(HC-=CH)` reacts with sodium in two steps to form monosodium acetylide `(HC-=CNa)` and disodium acetylide `(NaC-=CNa)` respectively and in each case, `H_2` is evolved.
`2[HC-=CH]+2Naoverset(Delta)to2[HC-=CNa]+H_2uarr`
`2[HC-=CNa]+2Naoverset(Delta)to2NaC-=CNa+H_2uarr`
(b) When acetylene gas is passed through ammoniacal `Cu_2Cl_2 or AgNO_3` solution , metallic acetylide is precipitated in each case.
`C_2H_2+Cu_2Cl_2+2NH_4OHtounderset((red))(Cu_2C_2darr)+2NH_4Cl+2H_2O`
`C_2H_2+2AgNO_3+2NH_4OHtounderset((White))(Ag_2C_2darr)+2NH_4NO_3+2H_2O`
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • HYDROCARBONS

    CHHAYA PUBLICATION|Exercise SOLVED WBCHSE SCANNER|63 Videos
  • HYDROCARBONS

    CHHAYA PUBLICATION|Exercise SOLVED NCERT EXERCISE|43 Videos
  • HYDROCARBONS

    CHHAYA PUBLICATION|Exercise (QUESTION-ANSWER ZONE FOR BOARD EXAMINATION (Short answer type)|87 Videos
  • HALOAKANES AND HALOARENES

    CHHAYA PUBLICATION|Exercise Practise set 10 (Answer the following questions)|10 Videos
  • HYDROGEN

    CHHAYA PUBLICATION|Exercise PRACTICE SET -9|5 Videos

Similar Questions

Explore conceptually related problems

Give reaction to prove tha acidic character of acetylene.

How will you prove: presence of acetylenic hydrogen in 1-butyne.

How will you detect the presence of acetylene in a gas mixture ?

convert :Acetic acid from acetylene

How will you convert : Acetic acid to methane.

How will you prove: 2-butene is a symmetrical alkene.

How will you convert: Benzoic acid to benzal delyde

How does the acidic character of the oxides of group - 15 elements change the group ? Wjhy ?

How will you convert: Formic acid to oxallic acid.

How will you convert: Aniline to Benzoic acid