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Convert benzene into aniline by using th...

Convert benzene into aniline by using the following reagents in correct : alkaline `KMnO_4` and then HCl, `NH_3`, heat, `Br_2//KOH,CH_3Cl` /anhydrous `AlCl_3`.

Text Solution

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`{:(C_(6)H_(6) underset(underset(AlCl_(3))("Anhydrous"))overset(CH_(3)Cl)rarr underset("Toluene")(C_(6)H_(5)CH_(3)) underset((ii) dil. HCl)overset((i) "Alkaline "KMnO_(4))rarr underset("Benzoic acid")(C_(6)H_(5)COOH)),(" "darr NH_(3)", "Delta),(" "underset("Aniline")(C_(6)H_(5)NH_(2))overset(Br_(2)//KOH)larr underset("Benzamide")(C_(6)H_(5)CONH_(2))):}`
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Knowledge Check

  • Which one of the following is an intermediate in the reaction of benzene with CH_3Cl in the presence of anhydrous AlCl_3 ?

    A
    `Cl^+`
    B
    `CH_3^-`
    C
    `CH_3^+`
    D
    CH3

  • Which of the following reagents can be used for the reduction of CH_3COOH to CH_3CH_2 OH ?

    A
    `LiaIH_4//H_2O`
    B
    `B_2H_6//H^+`
    C
    `H_2//Pd`
    D
    `NaBH_4`

  • Which of the following reagents can be used for the reduction of CH_3COOH to CH_3CH_2 OH ?

    A
    `LiaIH_4//H_2O`
    B
    `B_2H_6//H^+`
    C
    `H_2//Pd`
    D
    `NaBH_4`

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