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Equivalent conductivity of NaCl at conce...

Equivalent conductivity of `NaCl` at concentration C and at infinite dilution are `lambda_(C) and lambda_(oo)` respectively. The correct relationship between `lambda_(C) and lambda_(oo)` is given as -

A

`lambda_(C)=lambda_(oo)+(B)sqrtC`

B

`lambda_(C)=lambda_(oo)+(B)C`

C

`lambda_(C)=lambda_(oo)-(B)C`

D

`lambda_(C)=lambda_(oo)-(B)sqrtC`

Text Solution

Verified by Experts

The correct Answer is:
D

According to Debye - Huckel theory, for strong electrocyte like `NaCl, lambda_(C)=lambda_(oo)-(B)sqrtC.`
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