Home
Class 12
CHEMISTRY
Dialkyl cadmium is used to prepare keton...

Dialkyl cadmium is used to prepare ketones from acid chlorides and not from Grignard reagents. Assign reason.

Text Solution

Verified by Experts

Grigard reagents do from ketones with acid chlorides but the reactions does not stop at this stage. Ketones further takes part in the reactions with Grignard reagents to give tertiary alcohols. Therefore, dialkyl cadmium is used which reacts with only the acid chlorides and not with ketones. For details consult sections 6.
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES AND KETONES

    DINESH PUBLICATION|Exercise Question From Board|86 Videos
  • ALDEHYDES AND KETONES

    DINESH PUBLICATION|Exercise Higher Order Thinking Skills|6 Videos
  • ALDEHYDES AND KETONES

    DINESH PUBLICATION|Exercise Problem|15 Videos
  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise Matrix|9 Videos
  • ALKALI EARTH METALS

    DINESH PUBLICATION|Exercise Unit test-12|5 Videos

Similar Questions

Explore conceptually related problems

Which of these do not from Grignard reagent ?

From Grignard Reagents And Carbon Dioxide

Grignard reagents are prepared in

Grignard reagent can be prepared by

Which of the following acids cannot be prepared from Grignard reagents?

Preparation and properties of Grignard Reagent

DINESH PUBLICATION-ALDEHYDES AND KETONES -Additional Important Question
  1. Carbonyl compounds are more polar than alcohols although electronegati...

    Text Solution

    |

  2. Dialkyl cadmium is used to prepare ketones from acid chlorides and no...

    Text Solution

    |

  3. In the preparation of aldehydes from primary alcohols, aldehydes forme...

    Text Solution

    |

  4. Boiling points of carbonyl compounds lie between the parent alkanes an...

    Text Solution

    |

  5. Give reasons in one or two sentances for the following: 'Hydrazones of...

    Text Solution

    |

  6. Iodoform is prepared by reacting acetone with hypoiodite and not with...

    Text Solution

    |

  7. Halogen acids readily combine with alkenes to form addition products b...

    Text Solution

    |

  8. Why does pure HCN fail to react with aldehydes and ketones ?

    Text Solution

    |

  9. Sodium bisulphite is used to purify aldehydes and ketones. Explain.

    Text Solution

    |

  10. Out of benzaldehyde and propionaldehyde, which is mre reactive towards...

    Text Solution

    |

  11. Boiling points of ketones are higher than those of the isomeric aldehy...

    Text Solution

    |

  12. Chloral hydrate is a gem-diol but still stable. How will you account f...

    Text Solution

    |

  13. Ketones are less reactive than aldehydes in the nucleophilic addition ...

    Text Solution

    |

  14. Why does not formaldehyde take part in aldol condensation?

    Text Solution

    |

  15. Why is it necessary to control the pH during the reaction of aldehydes...

    Text Solution

    |

  16. Benzophenone does not react with NaHSO(3). Explain.

    Text Solution

    |

  17. Why does formaldehyde undergo Cannizzaro's reaction while acetaldehyde...

    Text Solution

    |

  18. How wil you convert an alkene into an aldehyde containing one carboon ...

    Text Solution

    |

  19. Outline the synthesis of PhCH(2)CH(2)CHO from benzene, ethylene oxide ...

    Text Solution

    |

  20. How will you bring about the following changes :

    Text Solution

    |