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In the reaction PCl(5)(g) hArr PCl(3)(...

In the reaction
`PCl_(5)(g) hArr PCl_(3)(g)+Cl_(2)(g)`, the equilibrium concentrations of `PCl_(5)` and `PCl_(3)` are 0.4 and 0.2 mole `//` litre respectively. If the value of `K_(c)` is 0.5 , what is the concentration of `Cl_(2)` in moles `//` litre ?

A

2

B

1.5

C

1

D

0.5

Text Solution

Verified by Experts

The correct Answer is:
C

`PCl_(5)(g) hArr PCl_(3)(g) +Cl_(2)(g)`
`K_(c )=([PCl_(3)][Cl_(2)])/([PCl_(5)])`
`0.5=((0.2)[Cl_(2)])/((0.4))`
` [Cl_(2)]=(0.5xx0.4)/(0.2)=(0.20)/(0.2)=1.0 "mol " L^(-1)`
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