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The equilibrium: P(4)(g)+6Cl(2)(g) hAr...

The equilibrium:
`P_(4)(g)+6Cl_(2)(g) hArr 4PCl_(3)(g)`
is attained by mixing equal moles of `P_(4)` and `Cl_(2)` in an evacuated vessel. Then at equilibrium:

A

`[Cl_(2)]gt [PCl_(3)]`

B

`[Cl_(2)] gt [P_(4)]`

C

`[P_(4)] gt [Cl_(2)]`

D

`[PCl_(3)] gt [P_(4)]`

Text Solution

Verified by Experts

The correct Answer is:
C

`{:(,P_(4)(g),+,6Cl_(2)(g),hArr,4PCl_(3)(g)),("Initial",c"mol",,c "mol" ,,),("At eqm.",C(1-alpha),,C(1-6alpha),,4C alpha):}`
Clearly, `[P_(4)] gt [Cl_(2)]` at equilibrium
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