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A schematic plot of In K(eq) versus inve...

A schematic plot of In `K_(eq)` versus inverse o ftemperature for a reaction is shown below

the reaction must be:

A

exothermic

B

Endothermic

C

one with negligible enthalpy change

D

highly spontaneous at ordinary temperature

Text Solution

Verified by Experts

The correct Answer is:
A


Integrated form of van't Hoff equation
`ln K_(p)=-(DeltaH^(@))/(R )(1)/(T)+I`
The given line has a+ve slpe
`:. -(DeltaH^(@))/(R)gt0` ltbgt `implies DeltaH^(@) lt 0 ( :. R =0.0821 L ` atm `K^(-1)mol^(-1))`
Thus , the reaction is exothermic in nature.
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